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Нydrogenation of 4-nitrophenol on the catalysts containing oxides of rare-earth elements

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Abstract

The activity of the platinum (1%) catalysts supported on oxides of rare-earth elements of the cerium and yttrium groups was studied. Under the liquid-phase hydrogenation conditions, the studied catalytic systems are characterized by a high selectivity and the yield of 4-aminophenol is close to quantitative. In terms of the initial hydrogenation rate of 4-nitrophenol the system 1%Pt/Dy2O3 is 4.9 times superior to the standard 1%Pt/Al2O3 catalyst, whereas the system 1%Pt/Ce2O3 is 1.4 times more active than the standard catalyst.

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Authors and Affiliations

  1. Volzhsky Polytechnic Institute (Branch), Volgograd State Technical University, 42a ul. Engel’sa, Volzhsky, 404121, Volgograd Region, Russian Federation

    G. M. Kurunina, O. M. Ivankina, E. A. Perevalova & G. M. Butov

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  1. G. M. Kurunina
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  2. O. M. Ivankina
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  3. E. A. Perevalova
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  4. G. M. Butov
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Correspondence to G. M. Kurunina.

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No human or animal subjects were used in this research.

Based on the materials of the VI International Scientific Practical Conference “Modern Synthetic Methodologies for Development of Drugs and Functional Materials” (MOSM 2022) (November 7–11, 2022, Ekaterinburg, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 8, pp. 1929–1932, August, 2023.

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Kurunina, G.M., Ivankina, O.M., Perevalova, E.A. et al. Нydrogenation of 4-nitrophenol on the catalysts containing oxides of rare-earth elements. Russ Chem Bull 72, 1929–1932 (2023). https://doi.org/10.1007/s11172-023-3978-8

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  • DOI: https://doi.org/10.1007/s11172-023-3978-8

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