Abstract
Polymer complexes of the composition {[Cu2(fur)4(bpy)]n • nMeOH} (1) and {[Ag3(fur)(bpy)4]n•2nfur·13.5nH2O} (2) were synthesized by the reactions of copper(ii) and silver(i) acetates, respectively, with anions of furancarboxylic acid (Hfur) and 4,4’-bi-pyridine (bpy) under different synthesis conditions. The structures of the new complexes were established by X-ray diffraction (XRD) analysis. According to the XRD data, complex 1 is a polymer, in which the molecular metal oxide moieties are connected in a monodentate manner through bpy to form a 1D structural motif. The coordination environment of the copper(ii) atom in complex 1 can be described as a square pyramid {CuO4N}; the coordination number is 5. ionic complex 2 contains three nonequivalent Agi atoms in different coordination environment with different coordination numbers of the complexing metal (CNAg(1) = 4; CNAg(2)Ag(3) = 2). The supramolecular level of complex 2 is a 3D structure stabilized by different types of interactions, such as hydrogen bonds, π-stacking and ar-gentophilic interactions. The simultaneous thermal analysis demonstrated that complex 1 undergoes desolvation and decarboxylation at temperatures below 234 °C, whereas the bipyridine moieties coordinated to the copper(ii) atoms are not completely eliminated even at 500 °C. The in vitro biological activity of complexes 1 and 2 was evaluated against the non-pathogenic mycobacterial strain Mycolicibacterium smegmatis.
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Based on the materials of the Vi International Conference “Modern Synthetic Methodologies for Creating Drugs and Functional Materials” (MOSM 2022) (November 7–11, 2022, Yekaterinburg, Russia).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 8, pp. 1894–1904, August, 2023.
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Koshenskova, K.A., Baravikov, D.E., Khoroshilov, A.V. et al. Polymer Cu2+ and Ag+ furancarboxylate complexes with 4,4’-bipyridine: synthetic approaches, structure, thermal behavior, and biological activity. Russ Chem Bull 72, 1894–1904 (2023). https://doi.org/10.1007/s11172-023-3974-z
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DOI: https://doi.org/10.1007/s11172-023-3974-z