Abstract
The possibilities of fabrication and properties of new furan-containing polymers based on 5-hydroxymethylfurfural (5-HMF) and nitrogen-containing co-monomers (urea and melamine) have been studied. Two series of polymers, namely, 5-HMF-melamine and 5-HMF-urea at different ratios of the furan component: melamine (urea) were obtained. The effect of temperature in the range of 80–180 °C on the degree of cross-linking of polymers was studied. The thermostability of polymers was investigated by the TGA method. The polymers were tested for fire resistance according to GOST 28157-89 standard. It is demonstrated that obtained materials show increased heat and fire resistance in comparison to similar urea- and melamine-formaldehyde resins. It is recommended to use the developed polymers as non-combustible heat-insulating materials.
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References
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This work was financially supported by the Russian Science Foundation (project No. 21-13-00177) using the equipment of the Center for Collective Use “Nanotechnologies” of the M. I. Platov South-Russian State Polytechnic University (NPI).
No human or animal subjects were used in this research.
The authors declare no competing interests.
Based on the materials of the XVIII International Research and Development Conference “Novel Polymeric Composites. Mikitaev Readings” (July 4–9, 2022; p. Elbrus, Russia).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 6, pp. 1478–1481, June, 2023.
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Kataria, Y.V., Kashparova, V.P., Tokarev, D.V. et al. New furan based amino plastics: synthesis, properties and applications. Russ Chem Bull 72, 1478–1481 (2023). https://doi.org/10.1007/s11172-023-3924-9
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DOI: https://doi.org/10.1007/s11172-023-3924-9