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Surface modification of polymers using cationic polyelectrolyte solutions

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Abstract

Surface modification of polystyrene and Nafion™ films with a cationic polyelectrolyte poly(diallyldimethylammonium chloride), or PDADMAC, through adsorption of the polyelectrolyte from its aqueous solutions was studied. It was established that the PDADMAC adsorption layers strongly adhere to the polystyrene films, thus hydrophilizing their surface. Attempts to modify the surface of Nafion™ films revealed that PDADMAC is localized in channels of the swollen polymer film without any noticeable effect on the characteristics of the film surface.

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Authors and Affiliations

  1. Department of Chemistry, Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    V. D. Dolzhikova, Yu. G. Bogdanova & V. G. Sergeyev

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  1. V. D. Dolzhikova
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  2. Yu. G. Bogdanova
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  3. V. G. Sergeyev
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Corresponding author

Correspondence to Yu. G. Bogdanova.

Additional information

This work was financially supported within the framework of the State Assignment for Scientific Research (CITIS No. 121031300084-1).

No human or animal subjects were used in this research.

The authors declare no competing interests.

Based on the materials of the XVIII International Research and Development Conference “Novel Polymeric Composites. Mikitaev Readings” (July 4–9, 2022; p. Elbrus, Kabardino-Balkarian Republic, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 6, pp. 1396–1404, June, 2023.

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Dolzhikova, V.D., Bogdanova, Y.G. & Sergeyev, V.G. Surface modification of polymers using cationic polyelectrolyte solutions. Russ Chem Bull 72, 1396–1404 (2023). https://doi.org/10.1007/s11172-023-3914-y

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