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Methods for controlling the texture of thin films of wedge-shaped amphiphilic compounds based on 2,3,4-tris(dodecyloxy)benzenesulfonic acid

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Abstract

A number of wedge-shaped amphiphilic mesogens, derivatives of 1,2,3-tris(dodecyloxy)-benzene, which are precursors of polymer ion conducting membranes, were synthesized. The synthesized compounds included asymmetric 2,3,4-tris(dodecyloxy)benzenesulfonic acid and its sodium and pyridine salts. The self-organization processes of the synthesized mesogens were studied in thin films at different temperatures. Thermotropic liquid crystalline properties of these compounds were studied by DSC method. The structure of the liquid crystalline phases was studied using polarized thermooptical microscopy and X-ray diffraction. The influence of an orientation of magnetic field vector on phase composition of thin films was analyzed. It was shown that the texture of mesogenic films containing different counterions can be controlled by a combination of heating and applying a magnetic field.

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Authors and Affiliations

  1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Science, 1 prosp. Akademika Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    D. V. Anokhin, L. L. Gur’eva, E. S. Pikalov, A. F. Abukaev & V. P. Tarasov

  2. Department of Chemistry, Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    D. V. Anokhin

  3. Department of Fundamental Physical and Chemical Engineering, Lomonosov Moscow State University, Build. 51, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    E. S. Pikalov

  4. Moscow Institute of Physics and Technology (National Research University), 9 Institutskii per., 141700, Dolgoprudnyi, Moscow Region, Russian Federation

    A. F. Abukaev

Authors
  1. D. V. Anokhin
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  2. L. L. Gur’eva
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  3. E. S. Pikalov
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  4. A. F. Abukaev
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  5. V. P. Tarasov
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Corresponding author

Correspondence to L. L. Gur’eva.

Additional information

The study was carried out using the equipment of the Analytical Center for Collective Usage of the Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences.

The study was performed in the framework of state tasks No. 0089-2019-0012 (state registration No. AAA-A19-119032690060-9) and No. 0089-2019-0002 (state registration No. AAAA-A19-119071190017-7).

No human or animal subjects were used in this research.

The authors declare no competing interests.

Based on the materials of the XVIII International Scientific and Practical Conference “New polymer composite materials. Mikitaev Readings” (July 4–9, 2022, p. Elbrus, Kabardino-Balkarian Republic, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 6, pp. 1388–1395, June, 2023.

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Anokhin, D.V., Gur’eva, L.L., Pikalov, E.S. et al. Methods for controlling the texture of thin films of wedge-shaped amphiphilic compounds based on 2,3,4-tris(dodecyloxy)benzenesulfonic acid. Russ Chem Bull 72, 1388–1395 (2023). https://doi.org/10.1007/s11172-023-3913-z

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  • DOI: https://doi.org/10.1007/s11172-023-3913-z

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