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Melt- and solution-processable thermoelastic poly(urethane-imide) copolymers

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Abstract

Poly(urethane-imide) copolymers (PUICs) possessing the properties of new-generation thermoplastic elastomers with high heat resistance and mechanical strength were synthesized from polycaprolactone, 2,4-toluene diisocyanate, aromatic dianhydride A, and aromatic diamines. The heat resistance and thermal stability of the PUIC films and moldings, as well as their mechanical properties under dynamic and static conditions were compared. The influence of the type of the samples (films or moldings) on their elastic properties was studied. It was demonstrated that PUICs can be melt-processed under conditions where thermal and shear stresses do not cause noticeable degradation of the polymer, which influences the properties of moldings.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp., 119991, Moscow, Russian Federation

    A. L. Didenko, V. E. Smirnova, A. S. Nesterova & V. V. Kudryavtsev

  2. Institute of Macromolecular Compounds, Russian Academy of Sciences, 31 Bolshoy prosp. V.O., 199004, St. Petersburg, Russian Federation

    A. L. Didenko, A. G. Ivanov, V. E. Smirnova, G. V. Vaganov, E. N. Popova, A. S. Nesterova, V. Y. Yelokhovsky, V. M. Svetlichnyi, V. E. Yudin & V. V. Kudryavtsev

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  1. A. L. Didenko
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  2. A. G. Ivanov
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  3. V. E. Smirnova
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  4. G. V. Vaganov
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  5. E. N. Popova
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  6. A. S. Nesterova
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  7. V. Y. Yelokhovsky
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  8. V. M. Svetlichnyi
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  9. V. E. Yudin
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  10. V. V. Kudryavtsev
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Corresponding author

Correspondence to A. L. Didenko.

Additional information

This work was financially supported by the Russian Science Foundation (Project No. 22-19-00831).

No human or animal subjects were used in this research.

The authors declare no competing interests.

Based on the materials of the XVIII International Research and Development Conference “Novel Polymeric Composites. Mikitaev Readings” (July 4–9, 2022; p. Elbrus, Kabardino-Balkarian Republic, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 6, pp. 1377–1387, June, 2023.

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Didenko, A.L., Ivanov, A.G., Smirnova, V.E. et al. Melt- and solution-processable thermoelastic poly(urethane-imide) copolymers. Russ Chem Bull 72, 1377–1387 (2023). https://doi.org/10.1007/s11172-023-3912-0

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  • DOI: https://doi.org/10.1007/s11172-023-3912-0

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