Abstract
A ZnII tetraarylporphyrin containing bidentate binding sites in para-positions of the meso-phenyl fragments of the macrocycle was synthesized and structurally characterized. Bis-chelate binding of the synthesized tetrapyrrole macrocyclic compounds to CuII cations to give cyclic tetramers was studied. Bottom-up self-assembly of porphyrin oligomers on the surface of graphene oxide treated quartz plates yielded polyporphyrin films whose structure was determined by physicochemical methods. The binding ability of the resulting Cu-coordinated porphyrin films toward imidazole-containing pharmaceuticals (Metronidazole, histamine, and histidine) was studied.
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The authors express their gratitude to the Center for Joint Use of Scientific Equipment “The Upper Volga Region Center of Physic-Chemical Research” (G. A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo) for providing access to the equipment for this research.
No human or animal subjects were used in this research.
The authors declare no competing interests.
Based on the materials of the XVIII International Research and Development Conference “Novel Polymeric Composites. Mikitaev Readings” (July 4–9, 2022; p. Elbrus, Kabardino-Balkarian Republic, Russia).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 6, pp. 1322–1333, June, 2023.
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Mamardashvili, G.M., Mamardashvili, N.Z. Design and binding ability of organometallic Zn porphyrin films toward imidazole derivatives. Russ Chem Bull 72, 1322–1333 (2023). https://doi.org/10.1007/s11172-023-3907-x
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DOI: https://doi.org/10.1007/s11172-023-3907-x