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An accessible catalytic system generated by mixing aqueous ammonia and iodine in CO2 addition to oxiranes

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Abstract

A catalytic system generated by mixing iodine and an aqueous ammonia solution can catalyze conversion of oxiranes and CO2 to five-membered organic carbonates within 5–12 h. This catalytic system performed better with substrates bearing the electron-withdrawing substituents; the silica additives and elevated CO2 pressure further accelerated the reaction.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Build. 1, 28 ul. Vavilova, 119334, Moscow, Russian Federation

    S. E. Lyubimov & P. V. Cherkasova

Authors
  1. S. E. Lyubimov
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  2. P. V. Cherkasova
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Corresponding author

Correspondence to S. E. Lyubimov.

Additional information

This work was performed in the framework of the State Task of the Ministry of Science and Higher Education of the Russian Federation (Registration No. 075-00697-22-00).

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 5, pp. 1259–1261, May, 2023.

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Lyubimov, S.E., Cherkasova, P.V. An accessible catalytic system generated by mixing aqueous ammonia and iodine in CO2 addition to oxiranes. Russ Chem Bull 72, 1259–1261 (2023). https://doi.org/10.1007/s11172-023-3898-7

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  • DOI: https://doi.org/10.1007/s11172-023-3898-7

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