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Synthesis of new bifunctional derivatives of 2,2′-biquinoline and their polymers and metal-polymer complexes with CuI

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Abstract

A method for the synthesis of new bifunctional biquinoline monomers, 2,2′-biquinoline-6,6′-, 7,7′-, and 8,8′-dicarboxylic acids, was developed. Copolyamic acids and copolybenzoxazinoneimides with biquinoline units in the main chain and their metalpolymer complexes with CuI were synthesized, and their mechanical, thermal, molecular, and electrochemical properties were studied.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, 31 Bolshoi prosp., 199004, St. Petersburg, Russian Federation

    M. Ya. Goikhman, I. V. Podeshvo, V. D. Krasikov, I. I. Malakhova, I. V. Gofman, N. L. Loretsyan, M. A. Smirnov, N. N. Smirnov, E. N. Vlasova, N. S. Gulii & A. V. Yakimanskii

Authors
  1. M. Ya. Goikhman
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  2. I. V. Podeshvo
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  3. V. D. Krasikov
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  4. I. I. Malakhova
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  5. I. V. Gofman
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  6. N. L. Loretsyan
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  7. M. A. Smirnov
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  8. N. N. Smirnov
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  9. E. N. Vlasova
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  10. N. S. Gulii
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  11. A. V. Yakimanskii
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Corresponding author

Correspondence to M. Ya. Goikhman.

Additional information

No human or animal subjects were used in this research.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 5, pp. 1150–1160, May, 2023.

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Goikhman, M.Y., Podeshvo, I.V., Krasikov, V.D. et al. Synthesis of new bifunctional derivatives of 2,2′-biquinoline and their polymers and metal-polymer complexes with CuI. Russ Chem Bull 72, 1150–1160 (2023). https://doi.org/10.1007/s11172-023-3883-1

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  • DOI: https://doi.org/10.1007/s11172-023-3883-1

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