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Synthesis of functionalized trimethylsilyl aminomethylphosphinates containing triethoxysilyl moieties

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Abstract

A convenient synthesis of functionalized trimethylsilyl aminomethylphosphinates containing triethoxysilyl moieties was developed. Radical addition of bis(trimethylsiloxy)-phosphine to triethoxy(vinyl)silane proceeds regioselectively to afford a novel synthon, (2-triethoxysilylethyl)phosphonite, subsequent aminomethylation of which gives the target phosphinates.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskiye Gory, 119991, Moscow, Russian Federation

    A. A. Prishchenko, M. V. Livantsov, O. P. Novikova & L. I. Livantsova

  2. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    S. V. Baranin & Yu. N. Bubnov

  3. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Build. 1, 28 ul. Vavilova, 119334, Moscow, Russian Federation

    Yu. N. Bubnov

Authors
  1. A. A. Prishchenko
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  2. M. V. Livantsov
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  3. O. P. Novikova
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  4. L. I. Livantsova
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  5. S. V. Baranin
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  6. Yu. N. Bubnov
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Corresponding author

Correspondence to S. V. Baranin.

Additional information

Dedicated to Academician of the Russian Academy of Sciences I. P. Beletskaya on the occasion of her anniversary.

No human or animal subjects were used in this research.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 4, pp. 1088–1092, April, 2023.

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Prishchenko, A.A., Livantsov, M.V., Novikova, O.P. et al. Synthesis of functionalized trimethylsilyl aminomethylphosphinates containing triethoxysilyl moieties. Russ Chem Bull 72, 1088–1092 (2023). https://doi.org/10.1007/s11172-023-3875-3

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  • DOI: https://doi.org/10.1007/s11172-023-3875-3

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