Abstract
The hydrolytic stability of polyimide films (PI) in a 0.9% sodium chloride solution in the temperature range of existing biological objects was studied. The kinetic parameters of hydrolysis of PI films were calculated. It was established that the hydrolysis rate constant of an adamantane-containing film was significantly lower than that of an industrial Kapton film. The dielectric constant after hydrolysis was determined. It was shown that the dielectric properties of the adamantane-containing polymer remained unchanged under the hydrolysis conditions.
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Dedicated to Academician of the Russian Academy of Sciences I. P. Beletskaya on the occasion of her anniversary.
This work was financially supported by the Volgograd State Technical University (Project No. 17/474-22).
The studies were carried out using equipment of the Center for Collective Use “Physicochemical Methods of Investigation” at the Volgograd State Technical University.
No human or animal subjects were used in this research.
The authors declare no competing interests.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 4, pp. 1036–1045, April, 2023.
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Novakov, I.A., Orlinson, B.S., Zav’yalov, D.V. et al. Experimental and theoretical studies of hydrolytic stability of transparent polyimide films. Russ Chem Bull 72, 1036–1045 (2023). https://doi.org/10.1007/s11172-023-3869-6
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DOI: https://doi.org/10.1007/s11172-023-3869-6