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Supramolecular Ru nanocatalyst, based on a β-cyclodextrin copolymer with epichlorohydrin, in the hydrogenation of unsaturated compounds

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Abstract

A water-soluble catalyst based on ruthenium(0) nanoparticles stabilized with copolymer based on β-cyclodextrin and epichlorohydrin was synthesized and characterized by transmission electron microscopy, small-angle X-ray scattering, and X-ray photoelectron spectroscopy. The catalyst obtained was tested in the hydrogenation of various substrates, such as aromatic and unsaturated compounds, phenols, levulinic acid and its esters for the first time. The catalyst activity was found to depend considerably on the substrate polarity and size. The size of the non-polar moiety of the substrate was that specifying its propensity to form inclusion complexes with β-cyclodextrin moieties of the carrier. For aromatic compounds, the latter acted as a protecting group.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp., 119991, Moscow, Russian Federation

    A. L. Maximov, A. V. Zolotukhina & E. R. Naranov

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  1. A. L. Maximov
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  2. A. V. Zolotukhina
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  3. E. R. Naranov
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Correspondence to A. V. Zolotukhina.

Additional information

Dedicated to Academician of the Russian Academy of Sciences I. P. Beletskaya on the occasion of her anniversary.

The authors are grateful to R. S. Borisov (A. V. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences (TIPS RAS)) for assistance in carrying out mass spectrometry, M. A. Topchii (TIPS RAS) for performing NMR analysis, A. A. Gud and A. A. Tereshchenko (National Research Center “Kurchatov Institute”, Moscow) for carrying out analysis by small-angle X-ray scattering.

The work was financially supported by the Ministry of Science and Higher Education of the Russian Federation (Agreement No. 075-15-2021-1363).

No human or animal subjects were used in this research.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 4, pp. 853–872, April, 2023.

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Maximov, A.L., Zolotukhina, A.V. & Naranov, E.R. Supramolecular Ru nanocatalyst, based on a β-cyclodextrin copolymer with epichlorohydrin, in the hydrogenation of unsaturated compounds. Russ Chem Bull 72, 853–872 (2023). https://doi.org/10.1007/s11172-023-3849-4

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