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Supramolecular structures of new tetranuclear hydroxypiperidine iodoantimonates(iii)

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Abstract

Two new hybrid iodoantimonates(iii), (3-C5H12NO)4[Sb4I16] · 2 H2O (1, 3-C5H12NO+ is 3-hydroxypiperidinium) and (4-C5H12NO)4[Sb4I16] · 3 H2O (2, 4-C5H12NO+ is 4- hydroxypiperidinium), were synthesized. Their crystal structures were established. The anionic substructures of the new compounds are composed of the same tetranuclear complex anions [Sb4I16]4−. The differences in the structure of 3-hydroxypiperidine and 4-hydroxypiperidine are responsible for the differences in the supramolecular organization of the cationic substructures and in the packing of the structural units. The comparative analysis of hydrogen bonding systems in the structures of compounds 1 and 2 was carried out. The band gap width for compound 1 was estimated at 2.38 eV according to the direct band gap model and at 2.28 eV in terms of the indirect band gap model.

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Authors and Affiliations

  1. Department of Chemistry, Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    A. A. Vasiliev, A. V. Bykov, T. A. Shestimerova, M. A. Bykov & A. V. Shevelkov

  2. P. N. Lebedev Physical Institute, Russian Academy of Sciences, 53 Leninsky prosp., 119991, Moscow, Russian Federation

    V. E. Goncharenko

Authors
  1. A. A. Vasiliev
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  2. A. V. Bykov
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  3. T. A. Shestimerova
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  4. M. A. Bykov
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  5. V. E. Goncharenko
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  6. A. V. Shevelkov
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Corresponding author

Correspondence to A. V. Shevelkov.

Additional information

Dedicated to Academician of the Russian Academy of Sciences I. P. Beletskaya on the occasion of her anniversary.

This work was financially supported by the Russian Foundation for Basic Research (Project No. 20-03-00280). We are grateful to A. V. Grigorieva for help in performing spectroscopic studies. The X-ray diffraction studies were carried out using the equipment granted by the Lomonosov Moscow State University Program of Development.

No human or animal subjects were used in this research.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 3, pp. 641–650, March, 2023.

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Vasiliev, A.A., Bykov, A.V., Shestimerova, T.A. et al. Supramolecular structures of new tetranuclear hydroxypiperidine iodoantimonates(iii). Russ Chem Bull 72, 641–650 (2023). https://doi.org/10.1007/s11172-023-3828-1

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  • DOI: https://doi.org/10.1007/s11172-023-3828-1

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