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Preparation of heterogeneous catalysts by the post-synthetic modification of mesoporous metal-organic framework MIL-101

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Abstract

A series of MIL-101-L compounds (L = 4,4′-bipyridyl, pyrazine, piperazine, 1,4-diaza[2.2.2]bicyclooctane, and ethylenediamine) was synthesized using the post-synthetic coordination modification of mesoporous chromium(iii) terephthalate MIL-101. These compounds contain basic sites and are capable of exhibiting catalytic activity in the Henry nitroaldol condensation reaction with high selectivity. Compounds MIL-101-Sal-M (M = Ni, Cr, Zr, Co) containing the salen complexes grafted onto the framework surface were prepared using the covalent post-synthetic modification methods. These compounds exhibit catalytic activity in the addition of carbon dioxide to propylene oxide in quantitative yield in the presence of a cocatalyst. The results obtained confirm that the post-synthetic modification of porous metal-organic frameworks is an efficient approach for preparing heterogeneous catalysts based on the known homogeneous catalysts.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 3 prosp. Akad. Lavrent’eva, 930090, Novosibirsk, Russian Federation

    P. V. Burlak, K. A. Kovalenko & V. P. Fedin

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  1. P. V. Burlak
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  2. K. A. Kovalenko
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  3. V. P. Fedin
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Correspondence to K. A. Kovalenko or V. P. Fedin.

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Dedicated to Academician of the Russian Academy of Sciences I. P. Beletskaya on the occasion of her anniversary.

This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation (Project No. 121031700321-3).

No human or animal subjects were used in this research.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 3, pp. 624–634, March, 2023.

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Burlak, P.V., Kovalenko, K.A. & Fedin, V.P. Preparation of heterogeneous catalysts by the post-synthetic modification of mesoporous metal-organic framework MIL-101. Russ Chem Bull 72, 624–634 (2023). https://doi.org/10.1007/s11172-023-3826-8

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