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Regularities of aging of polymer and polymer composite materials in the conditions of the Far North

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Abstract

A review of studies on the aging of polymer and polymer composite materials (PCM) in the extremely cold climate of Yakutia is presented. The possibilities of modern instrumental methods (thermal analysis, colorimetry, fractography, profilometry, diffusion analysis, etc.) for revealing of the mechanisms of physicochemical transformations, taking into account the gradients of property indices over the thickness of samples at early stages of aging, are demonstrated. It has been established that the main causes of abnormal deterioration of the strength indicators of PCM in Arctic conditions are daily and seasonal thermal and moisture cycles, which cause growth of internal stresses and formation of microcracks in polymer matrices. The peculiarities of climatic aging of PCM with a combination of mechanical loads are considered. Combining the principles of the kinetics of molecular physical and chemical transformations and linear fracture mechanics is the basis for further progress in modeling and predicting the durability of PCM in the conditions of the Far North.

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Authors and Affiliations

  1. Federal Research Center Yakutsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences, 2 ul. Petrovskogo, 677980, Yakutsk, Russian Federation

    M. P. Lebedev & O. V. Startsev

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  1. M. P. Lebedev
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  2. O. V. Startsev
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Correspondence to O. V. Startsev.

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Mikhail Petrovich Lebedev, born in 1958, General Director of the Yakutsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences, an expert in the field of materials science and technology of inorganic materials. He has developed the principles for obtaining highly efficient macroheterogeneous materials. Main scientific results are technological procedure for the fabrication of a nanomodified binder in a composite, a new approach to control the structure and phase composition of sintered carbide diamond-containing powder mixtures, the synergism of the processes of destruction and biocorrosion of polymer composite materials under the influence of an extremely cold climate. Prof. Lebedev is the author of 304 scientific papers, including 7 monographs and 41 patents. He is the supervisor of students, graduate students, and Dr Sci applicants. Three Ph.D. thesis were defended under his supervision. Lebedev is Professor and Head of the Department of Mechanical Engineering of the M. K. Ammosov North East Federal University, Coordinator of Scientific Programs of the Russian Academy of Sciences and the Siberian Branch of the Russian Academy of Sciences, Member of the Presidium of the Siberian Branch of the Russian Academy of Sciences, Member of the Scientific Council on the Arctics and Antarctic at the Presidium of the Russian Academy of Sciences, Member of the Editorial Board of the journals “Chemical Technology” and “Natural resources of the Arctics and Subarctics”, a member of the dissertation council at Komsomolskon-Amur State Technical University.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 2, pp. 5531–565, February, 2023.

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Lebedev, M.P., Startsev, O.V. Regularities of aging of polymer and polymer composite materials in the conditions of the Far North. Russ Chem Bull 72, 553–565 (2023). https://doi.org/10.1007/s11172-023-3819-1

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