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One-dimensional europium coordination polymer with redox-active ligands

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Abstract

The one-dimensional (1D) coordination polymer [(dpp-bian)−Eu2+(4,4-bipy)−-(THF)2·4THF]n(1) (dpp-bian is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene; 4,4′-bipy is 4,4′-bipyridine) was synthesized by the oxidation of the complex [(dpp-bian)2−-Eu2+(THF)4] with neutral 4,4′-bipy in tetrahydrofuran (THF). According to the single-crystal X-ray diffraction analysis, the coordination polymer chain in 1 consists of alternating europium(II) ions and 4,4′-bipyridine radical anions. Acenaphthene-1,2-diimine dpp-bian acts as a terminal chelating radical-anion ligand. The europium(II) atom is coordinated by four nitrogen atoms and two oxygen atoms of THF molecules. According to the thermogravimetric analysis, the thermal decomposition of 1 occurs in four steps. An increase in the magnetic moment of compound 1 in the range from 40 to 5 K is due to the ferromagnetic exchange interaction between the spins of dpp-bian (S = 1/2) and 4,4′-bipy radical anions (S = 1/2) and the spin of the Eu2+ ion (S = 7/2).

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603137, Nizhny Novgorod, Russian Federation

    N. L. Bazyakina, M. V. Moskalev, R. V. Rumyantcev & I. L. Fedushkin

  2. International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    A. S. Bogomyakov & V. I. Ovcharenko

  3. Lobachevsky State University of Nizhny Novgorod, Build. 5, 23 prosp. Gagarina, 603022, Nizhny Novgorod, Russian Federation

    N. N. Smirnova & A. V. Markin

Authors
  1. N. L. Bazyakina
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  2. M. V. Moskalev
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  3. R. V. Rumyantcev
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  4. A. S. Bogomyakov
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  5. V. I. Ovcharenko
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  6. N. N. Smirnova
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  7. A. V. Markin
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  8. I. L. Fedushkin
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Corresponding authors

Correspondence to A. S. Bogomyakov or I. L. Fedushkin.

Additional information

Igor Leonidovich Fedushkin, born in 1966, Doctor of Chemical Sciences, Professor, Corresponding Member of the Russian Academy of Sciences since 2011, Director of the G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences (Nizhny Novgorod), expert in the field of coordination and physical organic chemistry, elected as an Academician of the Russian Academy of Sciences in 2022 (for more detailed information, see Ref. 1).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 2, pp. 507–517, February, 2023.

No human or animal subjects were used in this research.

The authors declare no competing interests.

The study was financially supported by the Russian Science Foundation (Project No. 19-13-00336-Π) and was performed using the equipment of the Center for Collective Use “Analytical Center of the IOMC RAS” (Grant “Ensuring the Development of the Material and Technical Infrastructure of the Centers for Collective Use of Scientific Equipment,” unique identifier RF—2296.61321X0017, agreement number 075-15-2021-670).

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Bazyakina, N.L., Moskalev, M.V., Rumyantcev, R.V. et al. One-dimensional europium coordination polymer with redox-active ligands. Russ Chem Bull 72, 507–517 (2023). https://doi.org/10.1007/s11172-023-3814-5

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  • DOI: https://doi.org/10.1007/s11172-023-3814-5

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