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Effect of the metal ion radius on the structure of SrII—ZnII and SrII—CdII complexes with cyclobutane-1,1-dicarboxylate anions

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Abstract

Strontium(II)—zinc(II) and strontium(II)—cadmium(II) coordination compounds with dianions of cyclobutane-1,1-dicarboxylic acid (H2cbdc) were synthesized. In the complexes [Sr4Zn4(cbdc)8(H2O)9]n(1) and {[SrCd(cbdc)2(H2O)3] · 3H2O}n(2), the cyclobutane-1,1-dicarboxylate dianions are coordinated to strontium atoms in a chelate fashion to form monomeric mono- and bischelate moieties, which link the d-metal atoms into a polymer structure. An increase in the ion radius of the d-metal in going from zinc(II) to cadmium(II) is accompanied by a decrease in the dimensionality of the coordination polymer from layered to chain.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    E. N. Zorina-Tikhonova, N. V. Gogoleva, A. S. Chistyakov, P. Y. Khapaeva, M. A. Shmelev, A. A. Sidorov, M. A. Kiskin & I. L. Eremenko

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  1. E. N. Zorina-Tikhonova
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  2. N. V. Gogoleva
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Correspondence to E. N. Zorina-Tikhonova.

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This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation as part of the State Assignment of the N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences.

No human or animal subjects were used in this research.

The authors declare no competing interests.

Aleksei Anatolievich Sidorov, born in 1957, Chief Researcher at the N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Professor, Candidate for Corresponding Member of the Russian Academy of Sciences in the elections of 2022, expert in coordination chemistry, author and co-author of 350 scientific publications. He contributed to the development of the chemistry of homometallic and heterometallic polynuclear carboxylate complexes. A. A. Sidorov is the Deputy Editor-in-Chief of the Russian Journal of Coordination Chemistry, a member of the Academic Council of the IGIC RAS, the Vice Chairman of the Dissertation Council on inorganic Chemistry of the IGIC RAS for defending Ph. D. and Doctor of Science degrees.

Mikhail Aleksandrovich Kiskin, born in 1980, Doctor of Chemical Sciences, Leading Researcher at the N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, winner of the XV competition of the European Academy for young scientists of Russia, Candidate for Corresponding Member of the Russian Academy of Sciences in the elections of 2022, expert in coordination chemistry, author and co-author of 307 scientific publications and three patents. He developed methods for the synthesis of heterometallic carboxylate compounds based on combinations of stable homo- and heterometallic moieties, serving as building blocks for the directed self-assembly of new metal-organic frameworks, functional components for the modification of aerogels, and precursors of bulk and/or nanosized complex metal oxides and thin-film materials based on these compounds. M. A. Kiskin is a member of the Academic Council of the IGIC RAS, a member of the Higher Attestation Commission at the Ministry of Science and Higher Education of the Russian Federation, a member of the Expert Council for the Presidential Program of the Russian Science Foundation.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 1, pp. 184–192, January, 2023.

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Zorina-Tikhonova, E.N., Gogoleva, N.V., Chistyakov, A.S. et al. Effect of the metal ion radius on the structure of SrII—ZnII and SrII—CdII complexes with cyclobutane-1,1-dicarboxylate anions. Russ Chem Bull 72, 184–192 (2023). https://doi.org/10.1007/s11172-023-3723-3

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