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Asymmetric organocatalysis: from a breakthrough methodology to sustainable catalysts and processes

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Abstract

The evolution of modern catalytic methodologies for asymmetric organic synthesis, including transition metal and organocatalysis, is briefly considered. The results of the authors’ research group comprise the development of convenient, efficient, and reusable metal-free amine-containing catalysts (aminocatalysts) for manufacturing enantiomerically enriched organic compounds. The efficiency of the obtained catalysts is demonstrated for asymmetric aldol reactions, Michael reactions, and domino reactions, including green chemistry processes. The applicability of the developed catalysts and processes for the synthesis of natural product analogs and the most active enantiomers of clinically used drugs is demonstrated.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninskii prosp., 119991, Moscow, Russian Federation

    A. S. Kucherenko & S. G. Zlotin

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  1. A. S. Kucherenko
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  2. S. G. Zlotin
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Correspondence to S. G. Zlotin.

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No human or animal subjects were used in this research.

The authors declare no competing interests.

Sergei Grigor’evich Zlotin, born in 1952, Head of I. N. Nazarov laboratory of fine organic synthesis at the N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Doctor of Chemical Sciences, Professor. S. G. Zlotin was elected Corresponding Member of the Russian Academy of Sciences in 2022 (for more detailed information, see Russ. Chem. Bull, 2022, 71, 1559; DOI: 10.1007/s11172-022-3565-4).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 1, pp. 42–60, January, 2023.

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Kucherenko, A.S., Zlotin, S.G. Asymmetric organocatalysis: from a breakthrough methodology to sustainable catalysts and processes. Russ Chem Bull 72, 42–60 (2023). https://doi.org/10.1007/s11172-023-3713-5

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  • DOI: https://doi.org/10.1007/s11172-023-3713-5

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