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Synthesis, structure, and luminescent properties of neutral tris-complexes of Eu3+ and Sm3+ with 4,4,5,5,6,6,6-heptafluoro-1-(1-methyl-1H-pyrazol-4-yl)hexane-1,3-dione

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Abstract

The reaction of 4,4,5,5,6,6,6-heptafluoro-1-(1-methyl-1H-pyrazol-4-yl)hexane-1,3-dione (HPyrC3F7) with freshly precipitated hydrated europium(ɪɪɪ) and samarium(ɪɪɪ) hydroxides in EtOH afforded crystalline complexes of the composition [Ln(PyrC3F7)3(EtOH)2], the features of their formation depending on the stoichiometric ligand/metal ratios were studied. The structure and composition of the complexes were characterized by physicochemical methods, including single-crystal X-ray diffraction. The luminescent properties of these compounds in the crystalline state and in solutions were studied in detail. Possible ways of transferring electronic excitation in the complex [Eu(PyrC3F7)3(EtOH)2] were considered.

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Funding

This work was financially supported by the Russian Science Foundation (Project No. 19-13-00272). X-ray diffraction analysis of complexes was performed on the equipment of the Center for Collective Use of Physical Research Methods of the N. S. Kurnakov Institute of General and Inorganic Chemistry of RAS in the framework of the Russian state assignment for the IGIC RAS in the field of fundamental scientific research.

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Authors and Affiliations

  1. P. N. Lebedev Physical Institute, Russian Academy of Sciences, 53 Leninsky prosp., 119991, Moscow, Russia

    M. T. Metlin, Yu. A. Belousov, N. P. Datskevich, V. M. Korshunov, D. A. Metlina & I. V. Taydakov

  2. Department of Chemistry, Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russia

    Yu. A. Belousov

  3. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russia

    M. A. Kiskin

  4. G. V. Plekhanov Russian University of Economics, 36 Stremyannoy per., 117997, Moscow, Russia

    I. V. Taydakov

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  1. M. T. Metlin
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  5. V. M. Korshunov
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Correspondence to I. V. Taydakov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2187–2198, October, 2022.

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Metlin, M.T., Belousov, Y.A., Datskevich, N.P. et al. Synthesis, structure, and luminescent properties of neutral tris-complexes of Eu3+ and Sm3+ with 4,4,5,5,6,6,6-heptafluoro-1-(1-methyl-1H-pyrazol-4-yl)hexane-1,3-dione. Russ Chem Bull 71, 2187–2198 (2022). https://doi.org/10.1007/s11172-022-3645-5

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