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NMR thermosensor properties of lanthanide complexes with diethylenetriamine-N,N,N′,N″,N″-pentaacetic acid [Ln(H2O)(DTPA)]2− (Ln = Pr, Dy, Ho, Yb)

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Abstract

The temperature dependences of paramagnetic chemical shifts in the lanthanide complexes with diethylenetriamine-N,N,N′,N″,N″-pentaacetic acid [Ln(H2O)(DTPA)]2− (Ln = Pr, Dy, Ho, Yb) were studied by NMR spectroscopy. The dysprosium complex demonstrated the highest temperature sensitivity of chemical shifts d(δexp)/dT equal to 1.46 ppm K−1 at T = 306 K. The [Dy(H2O)(DTPA)]2− complex can be considered as the most promising thermosensor reagent for determining the local temperature in aqueous media and for advanced MRI diagnosis of diseases.

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Funding

This work was financially supported by the Russian Science Foundation (Project No. 20-63-46026).

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russia

    E. N. Zapolotsky & S. P. Babailov

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  1. E. N. Zapolotsky
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  2. S. P. Babailov
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Correspondence to S. P. Babailov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2165–2171, October, 2022.

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Zapolotsky, E.N., Babailov, S.P. NMR thermosensor properties of lanthanide complexes with diethylenetriamine-N,N,N′,N″,N″-pentaacetic acid [Ln(H2O)(DTPA)]2− (Ln = Pr, Dy, Ho, Yb). Russ Chem Bull 71, 2165–2171 (2022). https://doi.org/10.1007/s11172-022-3642-8

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