Abstract
The kinetics of consumption of styrene epoxide (2) and accumulation of benzaldehyde (3) catalyzed by sulfuric acid (1) in an alcohol medium was studied in a bubbling glass reactor in an oxygen atmosphere. The dependences of the rates of consumption of 2 and accumulation of 3 on the concentrations of reactants 1 and 2 are of the same type: V2 = k2[1]1[2]0, V3 = k3[1]1[2]0. Data indicating an important role of the anions of acid catalysts in the conversions of epoxides were obtained.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
R. E. Parker, N. S. Jsaacs, Chem. Rev., 1959, 59, 737; DOI: https://doi.org/10.1021/cr50028a006.
G. Berti, F. Bottari, P. L. Ferrarini, B. Macchia, J. Org. Chem., 1965, 30, 4091; DOI: https://doi.org/10.1021/jo01023a026.
J. Biggs, N. B. Chapman, A. F. Finch, V. Wray, J. Chem. Soc. (B), 1971, 1, 55; DOI: https://doi.org/10.1039/J29710000055.
L. V. Petrov, V. M. Solyanikov, Dokl. Phys. Chem., 1996, 350, 252.
M. G. Spirin, S. B. Brichkin, L. V. Petrov, Russ. Chem. Bull., 2016, 65, 2452; DOI: https://doi.org/10.1007/S11172-016-1605-7.
L. V. Petrov, V. M. Solyanikov, Petroleum Chemistry, 2011, 51, 458; DOI: https://doi.org/10.1134/S0965544111060144.
L. V. Petrov, V. M. Solyanikov, Petroleum Chemistry, 2000, 40, 399.
L. V. Petrov, V. M. Solyanikov, Petroleum Chemistry, 2012, 52, 327; DOI: https://doi.org/10.1134/S096554411205009X.
L. V. Petrov, V. M. Solyanikov, Russ. Chem. Bull., 2020, 69, 1869; DOI: https://doi.org/10.1007/S11172-020-2972-7.
L.V. Petrov, V.M. Solyanikov, Petroleum Chemistry, 1999, 39, 89.
L. V. Petrov, V. M. Solyanikov, Russ. Chem. Bull., 2015, 64, 107; DOI: https://doi.org/10.1007/S11172-015-0828-3.
L. V. Petrov, V. M. Solyanikov, Petroleum Chemistry, 2005, 45, 202.
S. P. Jacober, R. P. Hanzlik, J. Am. Chem. Soc., 1986, 108, 1594; DOI: https://doi.org/10.1021/ja00267a033.
A. Filippi, M. Speranza, Int. J. Mass Spectrometry, 1999, 185/186/187, 425; DOI: https://doi.org/10.1016/S1387-3806(98)14184-2.
L. V. Petrov, M. G. Spirin, V. M. Solyanikov, Russ. Chem. Bull., 2019, 68, 1499; DOI: https://doi.org/10.1007/S11172-019-2583-3.
L. V. Petrov, B. L. Psikha, M. G. Spirin, Russ. Chem. Bull., 2021, 70, 1560; DOI: https://doi.org/10.1007/S11172-021-3252-X.
Funding
This study was performed within a state assignment (State Registration Number AAAA-A19-119071890015-6).
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2139–2141, October, 2022.
No human or animal subjects were used in this research.
The authors declare no competing interests.
Rights and permissions
About this article
Cite this article
Petrov, L.V., Solyanikov, V.M. Trends in the sulfuric acid-catalyzed consumption of styrene epoxide in an alcohol medium. Russ Chem Bull 71, 2138–2141 (2022). https://doi.org/10.1007/s11172-022-3638-4
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11172-022-3638-4