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Effect of electrolytes on aggregation behavior and solubilization properties of hexadecylpiperidinium surfactants

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Abstract

Data characterizing the effect of electrolyte additives (sodium chloride and salicylate, polyacrylic acid) on the critical micelle concentration and the size of hexadecylpiperidinium surfactant aggregates, including those containing one or two hydroxyl groups, were obtained by tensiometry and dynamic light scattering methods. The solubilization effect of surfactant—electrolyte systems with respect to the hydrophobic dye probe Orange OT was evaluated. The conditions (pH, ratio of components) for the formation of soluble (nonstoichiometric) and insoluble (stoichiometric) polymer-colloidal complexes were determined for a surfactant—polyacrylic acid system.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    A. B. Mirgorodskaya, A. A. Tyryshkina, R. A. Kushnazarova, D. M. Kuznetsov & L. Ya. Zakharova

Authors
  1. A. B. Mirgorodskaya
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  2. A. A. Tyryshkina
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  3. R. A. Kushnazarova
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  4. D. M. Kuznetsov
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  5. L. Ya. Zakharova
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Corresponding author

Correspondence to A. B. Mirgorodskaya.

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No human or animal subjects were used in this research.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1907–1913, September, 2022.

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Mirgorodskaya, A.B., Tyryshkina, A.A., Kushnazarova, R.A. et al. Effect of electrolytes on aggregation behavior and solubilization properties of hexadecylpiperidinium surfactants. Russ Chem Bull 71, 1907–1913 (2022). https://doi.org/10.1007/s11172-022-3608-x

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  • DOI: https://doi.org/10.1007/s11172-022-3608-x

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