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Hydrolytic polycondensation of diethoxymethylsilane under pressure

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Abstract

The process of hydrolytic polycondensation of diethoxymethylsilane in water under pressure was investigated without the use of organic solvents in non-catalytic conditions and in carbonic acid. It is demonstrated that in both cases the process of the formation of methylsiloxane polymers proceeds with 100% conversion of the monomer and complete preservation of hydrosilyl groups. The conditions for the selective production of linear products were found.

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Authors and Affiliations

  1. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 70 Profsoyuznaya ul., 117393, Moscow, Russian Federation

    A. A. Kalinina, E. V. Talalaeva, N. G. Vasilenko & A. M. Muzafarov

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119334, Moscow, Russian Federation

    T. A. Pryakhina, M. A. Pigaleva, I. V. Elmanovich, M. O. Gallyamov & A. M. Muzafarov

  3. Faculty of Physics, M. V. Lomonosov Moscow State University, 1-2 Leninskie Gory, 119991, Moscow, Russian Federation

    I. V. Elmanovich & M. O. Gallyamov

Authors
  1. A. A. Kalinina
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  2. T. A. Pryakhina
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  3. E. V. Talalaeva
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  4. N. G. Vasilenko
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  5. M. A. Pigaleva
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  6. I. V. Elmanovich
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  7. M. O. Gallyamov
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  8. A. M. Muzafarov
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Corresponding author

Correspondence to A. A. Kalinina.

Additional information

Dedicated to Academician of the Russian Academy of Science V. A. Tartakovsky on the occasion of his 90th birthday.

This work was supported by the Russian Science Foundation (Project No. 21-73-30030). The study of the molecular weight characteristics of the products, the registration of 1H NMR and IR spectra were carried out with the support of the Ministry of Science and Higher Education of the Russian Federation using scientific equipment of the Center for Collective Use “Polymer Research Center” of Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences (FFSM-2021-0004).

No human or animal subjects were used in this research.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1648–1655, August, 2022.

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Kalinina, A.A., Pryakhina, T.A., Talalaeva, E.V. et al. Hydrolytic polycondensation of diethoxymethylsilane under pressure. Russ Chem Bull 71, 1648–1655 (2022). https://doi.org/10.1007/s11172-022-3574-3

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