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Borane reduction of carbon dioxide bound to diimine-supported aluminum hydrides

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Abstract

The borane reduction of carbon dioxide bound to aluminum hydrides supported by redox-active acenaphthene-1,2-diimine ligands, [{(dpp-bian)AlO2CH2}2] (1) (dpp-bian is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) and [(ArBIG-bian)Al(μ-OC(H)O)2-Li(thf)2] (2) (ArBIG-bian is 1,2-bis[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaph-thene), was explored. The reaction of 1 with dimethylaminoborane (1:2) in toluene gives the paramagnetic methoxy-containing aluminum complex [{(dpp-bian)Al(OMe)}2(μ-O)] (3), whereas 2 is inert toward BH3 • NHMe2, but the reduction of 2 with pinacolborane HBpin (1:4) affords the mixed derivative [(ArBIG-bian)Al(OCH3)(OBpin)Li(thf)2] (4). Compounds 3 and 4 were characterized by elemental analysis, EPR and NMR spectroscopy, IR spectroscopy, and X-ray diffraction. The energy parameters of the reaction of 1 with dimethylaminoborane were evaluated and the paramagnetic electronic ground state of molecule 3 was confirmed by quantum chemical calculations.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603137, Nizhny Novgorod, Russian Federation

    T. S. Koptseva, M. V. Moskalev, A. A. Skatova, A. A. Bazanov, E. V. Baranov, E. A. Rychagova, S. Yu. Ketkov & I. L. Fedushkin

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  1. T. S. Koptseva
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  2. M. V. Moskalev
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  3. A. A. Skatova
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  4. A. A. Bazanov
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  5. E. V. Baranov
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  6. E. A. Rychagova
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  7. S. Yu. Ketkov
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  8. I. L. Fedushkin
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Correspondence to I. L. Fedushkin.

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Dedicated to Academician of the Russian Academy of Sciences V. A. Tartakovsky on the occasion of his 90th birthday.

The study was financially supported by the Russian Science Foundation (Project No. 20-13-00052) and was carried out using the equipment of the Center for Collective Use “Analytical Center of the IOMC RAS” with the financial support by the Grant “Ensuring the Development of the Material and Technical Infrastructure of the Centers for Collective Use of Scientific Equipment” (unique identifier RF-2296.61321X0017, agreement number 075-15-2021-670).

No human or animal subjects were used in this research.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1626–1633, August, 2022.

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Koptseva, T.S., Moskalev, M.V., Skatova, A.A. et al. Borane reduction of carbon dioxide bound to diimine-supported aluminum hydrides. Russ Chem Bull 71, 1626–1633 (2022). https://doi.org/10.1007/s11172-022-3571-6

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  • DOI: https://doi.org/10.1007/s11172-022-3571-6

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