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Kinetic regularities of the synthesis of soluble polyimide by termal imidization of polyamic acid in solution

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Abstract

Kinetic regularities of the synthesis of soluble polyimide by cyclization of polyamic acid in solution are investigated. The effective rate constants for the reactions of decomposition and imidization of polyamic acid occurring during imidization are determined depending on temperature. It is demonstrated that the negative deviation of the kinetics of the imidization of polyamic acid in solution from the first-order reaction equation is basically due to the influence of the polyamic acid decomposition with the formation of terminal amino groups.

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Funding

The instrumental base of the Center for Collective Use “Center for Research of Polymers” of N. S. Enikolopov Institute of synthetic polymer materials, Russian Academy of Science was used.

The work was financially supported by the Russian Ministry of Science and Education (Project No. FFSM-2021-0006).

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Authors and Affiliations

  1. N. S. Enikolopov Institute of synthetic polymer materials, Russian Academy of Sciences, 70 ul. Profsoyuznaya, 117393, Moscow, Russian Federation

    A. V. Ustimov, A. Yu. Tsegelskaya, G. K. Semenova & A. A. Kuznetsov

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  1. A. V. Ustimov
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  2. A. Yu. Tsegelskaya
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  3. G. K. Semenova
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  4. A. A. Kuznetsov
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Corresponding author

Correspondence to A. V. Ustimov.

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No human or animal subjects were used in this research.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1284–1289, June, 2022.

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Ustimov, A.V., Tsegelskaya, A.Y., Semenova, G.K. et al. Kinetic regularities of the synthesis of soluble polyimide by termal imidization of polyamic acid in solution. Russ Chem Bull 71, 1284–1289 (2022). https://doi.org/10.1007/s11172-022-3532-0

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  • DOI: https://doi.org/10.1007/s11172-022-3532-0

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