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The mechanism of formation of 3-substituted phospholanes in the reaction of alumolanes with PhPCl2

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Abstract

A theoretically substantiated mechanism for the replacement of aluminum atom in 1-ethyl-3-butylalumolane by a phosphorus atom on treatment with PhPCl2 giving 3-butyl-1-phenylphospholane was proposed on the basis of DFT quantum chemical modeling of the possible reaction pathways and monitoring of the reaction by multinuclear 1H, 13C, 31P, and 27Al NMR spectroscopy.

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Funding

The structural studies were carried out at the Regional Center for the Collective Use of Unique Equipment “Agidel” of the Ufa Federal Research Center (UFRC), Russian Academy of Sciences.

This study was performed within the framework of the State Assignment for the Institute of Petrochemistry and Catalysis, UFRC RAS.

Author information

Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    T. V. Tyumkina, R. R. Nurislamova, A. L. Makhamatkhanova, L. M. Khalilov & U. M. Dzhemilev

Authors
  1. T. V. Tyumkina
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  2. R. R. Nurislamova
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  3. A. L. Makhamatkhanova
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  4. L. M. Khalilov
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  5. U. M. Dzhemilev
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Corresponding author

Correspondence to T. V. Tyumkina.

Additional information

No human or animal subjects were used in this research.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1143–1150, June, 2022.

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Tyumkina, T.V., Nurislamova, R.R., Makhamatkhanova, A.L. et al. The mechanism of formation of 3-substituted phospholanes in the reaction of alumolanes with PhPCl2. Russ Chem Bull 71, 1143–1150 (2022). https://doi.org/10.1007/s11172-022-3514-2

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  • DOI: https://doi.org/10.1007/s11172-022-3514-2

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