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Peculiarities of fluoride ion mobility and conductivity in solid solutions containing bismuth trifluoride, as studied by 19F NMR and impedance spectroscopies

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Russian Chemical Bulletin Aims and scope

Abstract

The results of studies of ion mobility and electrophysical properties of solid solutions containing bismuth trifluoride are analyzed and summarized. The influence of fluorides as constituents of solid solutions on the character of ion mobility and ionic conductivity is considered. Solid solutions with a conductivity of about 10−3−10−2 S cm−1 in the temperature range 400–550 K can be treated as promising basis for the synthesis of functional materials.

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Funding

This work was financially supported by the Russian Foundation for Basic Research (Project No. 20-03-00279) and within the framework of the State Assignment to the Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences (Contract No. 205-2019-0001).

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Authors and Affiliations

  1. Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences, 159 prosp. 100-letiya Vladivostoka, 690022, Vladivostok, Russian Federation

    V. Ya. Kavun, A. B. Slobodyuk, M. M. Polyantsev & V. K. Goncharuk

  2. Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences, 18 ul. Kutateladze, 630128, Novosibirsk, Russian Federation

    N. F. Uvarov

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  1. V. Ya. Kavun
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  2. N. F. Uvarov
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Correspondence to V. Ya. Kavun.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1059–1084, June, 2022.

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Kavun, V.Y., Uvarov, N.F., Slobodyuk, A.B. et al. Peculiarities of fluoride ion mobility and conductivity in solid solutions containing bismuth trifluoride, as studied by 19F NMR and impedance spectroscopies. Russ Chem Bull 71, 1059–1084 (2022). https://doi.org/10.1007/s11172-022-3509-z

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  • DOI: https://doi.org/10.1007/s11172-022-3509-z

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