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Decomposition of zinc (1-hydroxyethylidene)diphosphonate induced by aliphatic amines and ammonia. Molecular structures of ammonium (1-hydroxyethylidene)diphosphonates

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Abstract

A suspension of sparingly soluble zinc (1-hydroxyethylidene)diphosphonate ZnH2L•2H2O (H4L = MeC(OH)[P(O)(OH)2]2) is rapidly transformed into an aqueous solution when treated with ammonia or aliphatic amines (hexamethylenediamine, triethylamine, tert-butylamine, di-n-butylamine) containing no hydrophilic groups −OH and −(OCH2CH2)n−. The dissolution effect is due to the decomposition of the coordination polymer giving ammonium derivatives. Dehydrated dry powders of the corresponding ammonium compounds based on triethylamine, tert-butylamine, or di-n-butylamine rapidly dissolve in water to form transparent colorless solutions, whereas hexamethylenediamine and ammonia derivatives are poorly soluble. (1-Hydroxyethylidene)diphosphonic acid forms ammonium salts with hexamethylenediamine, triethylamine, and tert-butylamine. The molecular structures of these compounds are considered.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    V. V. Semenov, N. V. Zolotareva, O. V. Novikova, B. I. Petrov, N. M. Lazarev, G. K. Fukin & A. V. Cherkasov

  2. Lobachevsky State University of Nizhny Novgorod, 23 prosp. Gagarina, 603022, Nizhny Novgorod, Russian Federation

    E. N. Razov

  3. Mechanical Engineering Research Institute, Federal Research Center Institute of Applied Physics of the Russian Academy of Sciences, 85 ul. Belinskogo, 603024, Nizhny Novgorod, Russian Federation

    E. N. Razov

Authors
  1. V. V. Semenov
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  2. N. V. Zolotareva
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  3. O. V. Novikova
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  4. B. I. Petrov
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  5. N. M. Lazarev
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  6. G. K. Fukin
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  7. A. V. Cherkasov
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  8. E. N. Razov
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Corresponding authors

Correspondence to V. V. Semenov or E. N. Razov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 980–992, May, 2022.

The studies were performed within the framework of the state assignment (task No. 45.8 “Chemistry of Functional Materials”, registration number 0094-2016-0012) using the equipment of the Center for Collective Use “Analytical Center of the IOMC RAS” of the G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences with the financial support of the Federal Target Program “Research and Development in Priority Fields of the Science and Technology Complex of Russia for 20142020” (unique project identifier RFMEFI62120X0040). The single-crystal X-ray diff raction studies were performed within the framework of the state assignment (task No. 44.2, registration number AAAA-A16-116122110053-1) using the equipment of the Center for Collective Use of the Research and Education Center “Physics of Solid State Nanostructures” of the Lobachevsky State University of Nizhny Novgorod. Experiments using scanning electron microscopy were performed within the state assignment for the Institute of Applied Physics of the Russian Academy of Sciences for fundamental scientific research for 2019–2022 (task No. 0035-2019-0026, registration number 01201458049).

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Semenov, V.V., Zolotareva, N.V., Novikova, O.V. et al. Decomposition of zinc (1-hydroxyethylidene)diphosphonate induced by aliphatic amines and ammonia. Molecular structures of ammonium (1-hydroxyethylidene)diphosphonates. Russ Chem Bull 71, 980–992 (2022). https://doi.org/10.1007/s11172-022-3500-8

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  • DOI: https://doi.org/10.1007/s11172-022-3500-8

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