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Synthesis and structure of new europium(ɪɪɪ) and terbium(ɪɪɪ) coordination polymers with trans-1,4-cyclohexanedicarboxylic acid

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Abstract

Two new metal-organic frameworks of composition [Eu2(phen)2Cl2(chdc)2] • 1.1DMF• •0.7diox (1•1.1DMF•0.7diox, phen is 1,10-phenanthroline, DMF is N,N-dimethyl-formamide, diox is dioxane) and [Tb2(phen)2Cl2(chdc)2] • 2diox • 2H2O (2 • 2diox • 2H2O) were synthesized using the conformationally flexible alicyclic ligand, trans-1,4-cyclohexane-dicarboxylic acid (H2chdc). The mononuclear complex [Tb(phen)2(DEF)(H2O)Cl2]Cl (3, DEF is N,N-diethylformamide) was also prepared. The structures of the reaction products were determined by single-crystal X-ray diffraction. The compositions and nature of the compounds 1 • 0.6DMF• 2.5H2O and 2 • 0.5diox • 4H2O, which were obtained after the separation of single crystals from the mother liquor, were confirmed by IR spectroscopy, elemental analysis, and thermogravimetric analysis. Both these compounds are composed of the binuclear units {Ln2(phen)2Cl2(O2CR)4} and are rare examples of the coordination of a halide anion to the LnIII ion in the metal-organic framework. The three-dimensional packing of the layers in the structures of 1 and 2 contains voids with a total volume of 35 and 32%, respectively.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    P. A. Demakov & V. P. Fedin

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  1. P. A. Demakov
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  2. V. P. Fedin
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Correspondence to V. P. Fedin.

Additional information

Based on the materials of the XXVIII International Chugaev Conference on Coordination Chemistry (October 3–8, 2021, Tuapse, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 967–973, May, 2022. 1066-5285/22/7105-0967

The study was financially supported by the Ministry of Science and Higher Education of the Russian Federation (Project No. 121031700321-3).

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Demakov, P.A., Fedin, V.P. Synthesis and structure of new europium(ɪɪɪ) and terbium(ɪɪɪ) coordination polymers with trans-1,4-cyclohexanedicarboxylic acid. Russ Chem Bull 71, 967–973 (2022). https://doi.org/10.1007/s11172-022-3498-y

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