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Polymerization of penta-1,3-diene using cationic catalytic systems based on organoaluminum compounds

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Abstract

Cationic polymerization of penta-1,3-diene with catalytic systems based on organoaluminum compounds (AlEtCl2, AlEt2Cl, and AlEt3) in combination with isopropyl chloride makes it possible to synthesize completely soluble solid polymers in a high yield with the softening point in the range from 81 to 91 °C. The signals of carbon atoms of the head isopropyl groups connected with 1,4-trans-unit of polypentadiene were identified using 1H and 13C NMR spectroscopy with the T2 filter, as well as 1H, 13C HSQC and HMBC 2D NMR spectroscopy.

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Authors and Affiliations

  1. Institute of Ecology of the Volga River Basin, Russian Academy of Sciences, Samara Federal Research Scientific Center, Russian Academy of Sciences, 10 ul. Komzina, 445003, Togliatti, Russian Federation

    V. A. Rozentsvet, D. M. Ulyanova & N. A. Sablina

  2. State Research Institute of Chemistry and Technology of Organoelement Compounds, 38 sh. Entuziastov, 111123, Moscow, Russian Federation

    M. G. Kuznetsova

  3. St. Petersburg State University, 7–9 Universitetskaya nab., 199034, St. Petersburg, Russian Federation

    P. M. Tolstoy

Authors
  1. V. A. Rozentsvet
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  2. D. M. Ulyanova
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  3. N. A. Sablina
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  4. M. G. Kuznetsova
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  5. P. M. Tolstoy
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Corresponding author

Correspondence to V. A. Rozentsvet.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 787–795, April, 2022.

This work was carried out in the framework of state assignment (theme No. 1021060107217-0-1.6.19).

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Rozentsvet, V.A., Ulyanova, D.M., Sablina, N.A. et al. Polymerization of penta-1,3-diene using cationic catalytic systems based on organoaluminum compounds. Russ Chem Bull 71, 787–795 (2022). https://doi.org/10.1007/s11172-022-3479-1

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  • DOI: https://doi.org/10.1007/s11172-022-3479-1

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