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Cobalt-doped chalcopyrites CuInSe2: the synthesis and magnetic properties

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Abstract

Two series of samples of the composition CuIn1−XCoXSe2 (m-series) and Cu1−X/2In1−X/2CoXSe2 (d-series) were prepared by solid-state synthesis and their magnetic properties were investigated. It was shown that cobalt is much better incorporated into the chalcopyrite matrix of the d-series samples, thus providing the onset of paramagnetic properties. Quenching allows the concentration of the incorporated cobalt to increase, which leads to the onset of weak ferromagnetism.

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References

  1. A. Polman, M. Knight, E. C. Garnett, B. Ehrler, W. C. Sinke, Science, 2016, 352, aad4424; DOI: https://doi.org/10.1126/science.aad4424.

    Article  Google Scholar 

  2. T. D. Lee, A. U. Ebong, Renew. Sustain. Energy Rev., 2017, 70, 1286; DOI: https://doi.org/10.1016/j.rser.2016.12.028.

    Article  CAS  Google Scholar 

  3. J. Ramanujam, D. M. Bishop, T. K. Todorov, O. Gunawan, J. Rath, R. Nekovei, E. Artegiani, A. Romeo, Prog. Mater. Sci., 2020, 110, 100619; DOI: https://doi.org/10.1016/j.pmatsci.2019.100619.

    Article  CAS  Google Scholar 

  4. G. Regmi, A. Ashok, P. Chawla, P. Semalti, S. Velumani, S. N. Sharma, H. Castaneda, J. Mater. Sci. Mater. Electron., 2020, 31, 7286; DOI: https://doi.org/10.1007/s10854-020-03338-2.

    Article  CAS  Google Scholar 

  5. H. Ohno, Science, 1998, 281, 951; DOI: https://doi.org/10.1126/science.281.5379.951.

    Article  CAS  Google Scholar 

  6. H. Ohno, D. Chiba, F. Matsukura, T. Omiya, E. Abe, T. Dietl, Y. Ohno, K. Ohtani, Nature, 2000, 408, 944; DOI: https://doi.org/10.1038/35050040.

    Article  CAS  Google Scholar 

  7. D. Chiba, H. Yamanouchi, F. Hatsukura, H. Ohno, Science, 2003, 301, 943; DOI: https://doi.org/10.1126/science.1086608.

    Article  CAS  Google Scholar 

  8. L. Chen, X. Yang, F. Yang, J. Zhao, J. Misuraca, P. Xiong, S. von Molnár, Nano Lett., 2011, 11, 2584; DOI: https://doi.org/10.1021/nl201187m.

    Article  CAS  Google Scholar 

  9. T. Dietl, H. Ohno, F. Matsukura, Phys. Rev. B, 2001, 63, 195205; DOI: https://doi.org/10.1103/PhysRevB.63.195205.

    Article  Google Scholar 

  10. L. I. Koroleva, D. M. Zashchirinskii, T. M. Khapaeva, A. I. Morozov, S. F. Marenkin, I. V. Fedorchenko, R. Szymczak, J. Magn. Magn. Mater., 2011, 323, 2923; DOI: https://doi.org/10.1016/j.jmmm.2011.05.054.

    Article  CAS  Google Scholar 

  11. K. Sato, G. A. Medvedkin, T. Ishibashi, S. Mitani, K. Takanashi, Y. Ishida, D. D. Sarma, J. Okabayashi, A. Fujimori, T. Kamatani, H. Akai, J. Phys. Chem. Solids, 2003, 64, 1461; DOI: https://doi.org/10.1016/S0022-3697(03)00101-X.

    Article  CAS  Google Scholar 

  12. S. Choi, G. B. Cha, S. C. Hong, S. Cho, Y. Kim, J. B. Ketterson, S. Y. Jeong, G. C. Yi, Solid State Commun., 2002, 122, 165; DOI: https://doi.org/10.1016/S0038-1098(02)00094-7.

    Article  CAS  Google Scholar 

  13. H. Bouhani-Benziane, O. Sahnoun, M. Sahnoun, M. Driz, C. Daul, J. Magn. Magn. Mater., 2015, 396, 345; DOI: https://doi.org/10.1016/j.jmmm.2015.08.025.

    Article  CAS  Google Scholar 

  14. M. A. Zykin, E. V. Busheva, T. G. Aminov, G. G. Shabunina, N. N. Efimov, Russ. J. Inorg. Chem., 2022, 67, 150; DOI: https://doi.org/10.1134/S0036023622020188.

    Article  CAS  Google Scholar 

  15. J. Yao, B. W. Rudyk, C. D. Brunetta, K. B. Knorr, H. A. Figore, A. Mar, J. A. Aitken, Mater. Chem. Phys., 2012, 136, 415; DOI: https://doi.org/10.1016/j.matchemphys.2012.06.066.

    Article  CAS  Google Scholar 

  16. J. Yao, C. N. Kline, H. Gu, M. Yan, J. A. Aitken, J. Solid State Chem., 2009, 182, 2579; DOI: https://doi.org/10.1016/j.jssc.2009.07.014.

    Article  CAS  Google Scholar 

  17. T. G. Aminov, N. N. Efimov, G. G. Shabunina, V. M. Novotortsev, Inorg. Mater. (Engl. Transl.), 2012, 48, 569; DOI: https://doi.org/10.1134/S0020168512060027.

  18. S. Furuseth, A. Kjekshus, A. F. Andresen, V. Nordal, A. A. Lindberg, J. C. Craig, Acta Chem. Scand., 1969, 23, 2325; DOI: https://doi.org/10.3891/acta.chem.scand.23-2325.

    Article  CAS  Google Scholar 

  19. K. Adachi, K. Sato, M. Takeda, J. Phys. Soc. Japan, 1969, 26, 631; DOI: https://doi.org/10.1143/JPSJ.26.631.

    Article  CAS  Google Scholar 

  20. A. Teruya, F. Suzuki, D. Aoki, F. Honda, A. Nakamura, M. Nakashima, Y. Amako, H. Harima, K. Uchima, M. Hedo, T. Nakama, Y. Ōnuki, J. Phys. Conf. Ser., 2017, 807, 012001; DOI: https://doi.org/10.1088/1742-6596/807/1/012001.

    Article  Google Scholar 

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    M. A. Zykin & N. N. Efimov

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  1. M. A. Zykin
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  2. N. N. Efimov
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Correspondence to M. A. Zykin.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 701–706, April, 2022.

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Zykin, M.A., Efimov, N.N. Cobalt-doped chalcopyrites CuInSe2: the synthesis and magnetic properties. Russ Chem Bull 71, 701–706 (2022). https://doi.org/10.1007/s11172-022-3468-4

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  • DOI: https://doi.org/10.1007/s11172-022-3468-4

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