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Pyrolytic synthesis of nitrogen and silicon doped graphene nanoflakes

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Abstract

Heterosubstitution in graphene materials is a powerful tool for targeted variation of their structural and electronic characteristics. In this work, the template pyrolytic approach combined with the simultaneous doping with nitrogen and silicon atoms was used for the first time to synthesize graphene nanoflakes. It was found that materials co-doped with nitrogen and silicon can be obtained by sequential introduction of silicon and nitrogen, while simultaneous doping resulted in the incorporation of only nitrogen atoms into the structure of the graphene layers, with silicon atoms binding with oxygen. According to transmission electron microscopy, the resulting particles have a different structure depending on the synthesis method.

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Authors and Affiliations

  1. Department of Chemistry, Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    D. N. Stolbov, S. A. Chernyak, K. I. Maslakov, N. N. Kuznetsova & S. V. Savilov

  2. Ivanovo State University, 39 ul. Ermaka, 153012, Ivanovo, Russian Federation

    D. N. Stolbov

  3. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    S. V. Savilov

Authors
  1. D. N. Stolbov
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  2. S. A. Chernyak
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  3. K. I. Maslakov
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  4. N. N. Kuznetsova
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  5. S. V. Savilov
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Corresponding authors

Correspondence to S. A. Chernyak or S. V. Savilov.

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Dedicated to Academician of the Russian Academy of Sciences R. Z. Sagdeev on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 680–685, April, 2022.

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Stolbov, D.N., Chernyak, S.A., Maslakov, K.I. et al. Pyrolytic synthesis of nitrogen and silicon doped graphene nanoflakes. Russ Chem Bull 71, 680–685 (2022). https://doi.org/10.1007/s11172-022-3465-7

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  • DOI: https://doi.org/10.1007/s11172-022-3465-7

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