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Regularities of the catalytic influence of organic base on the formation of magnesium and zinc complexes of porphyrazines

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Abstract

The regularities of the catalytic influence of nitrogen-containing base and DMSO on the formation of porphyrazine complexes with magnesium acetylacetonate and magnesium and zinc acetates in benzene are considered. The acid-base interaction plays a key role in the complex formation process. A relationship between the catalytic activity of the base and its proton-acceptor capacity and structure is shown. The schemes of formation of magnesium and zinc complexes with porphyrazines in a benzene—nitrogen-containing base (DMSO) are presented. The peculiarities of the catalytic effect of DMSO on the reaction of porphyrazines with magnesium acetate in benzene are analyzed.

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Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, 7 Sheremetevskii prosp., 153000, Ivanovo, Russian Federation

    O. A. Petrov

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Correspondence to O. A. Petrov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 613–619, April, 2022.

This work was financially supported by the Grant of the Ivanovo State University of Chemistry and Technology (13-ISUCT-21).

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Petrov, O.A. Regularities of the catalytic influence of organic base on the formation of magnesium and zinc complexes of porphyrazines. Russ Chem Bull 71, 613–619 (2022). https://doi.org/10.1007/s11172-022-3459-5

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  • DOI: https://doi.org/10.1007/s11172-022-3459-5

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