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Addition of carbon dioxide to epoxides catalyzed by the mixtures of α-amino acids and iodine

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Abstract

We found a group of available and efficient catalysts for the addition reaction of CO2 to epoxides, which was formed by simple mixing of molecular iodine with α-amino acids. Analysis of the spectral characteristics of the proline—iodine mixture, which showed the highest activity, suggests its existence as an equilibrium structure such as [proline—I]+I−.

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Funding

This work was financially supported by the Russian Science Foundation (Project No. 19-43-02031).

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. E. Lyubimov, P. V. Cherkasova & R. R. Aysin

  2. Department of Chemistry, Indian Institute of Technology (Indian School of Mines), Dhanbad, 826004, India

    B. Chowdhury

Authors
  1. S. E. Lyubimov
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  2. P. V. Cherkasova
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  3. R. R. Aysin
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  4. B. Chowdhury
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Corresponding authors

Correspondence to S. E. Lyubimov or B. Chowdhury.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 408–411, February, 2022.

The authors are grateful to the Center for Molecular Structure Studies at the A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences of the Ministry of Science and Higher Education of the Russian Federation for conducting analyses by Raman spectroscopy and valuable advices.

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Lyubimov, S.E., Cherkasova, P.V., Aysin, R.R. et al. Addition of carbon dioxide to epoxides catalyzed by the mixtures of α-amino acids and iodine. Russ Chem Bull 71, 408–411 (2022). https://doi.org/10.1007/s11172-022-3427-0

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  • DOI: https://doi.org/10.1007/s11172-022-3427-0

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