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The use of triethanolamine ammonium salts as catalysts for the addition of carbon dioxide to epoxides

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Abstract

Ammonium derivatives of triethanolamine have been effectively used as catalysts for the addition of CO2 to epoxides. The iodine additive was found to exert a positive effect on the catalytic activity of these polyhydroxy-containing salts.

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Funding

This work was financially supported by the Russian Science Foundation (Project No. 19-43-02031). The authors are grateful to the staff of the Center for Molecular Structure Studies at the A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences of the Ministry of Science and Higher Education of the Russian Federation for conducting NMR experiments and valuable advices.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. E. Lyubimov & P. V. Cherkasova

  2. Department of Chemistry, Indian Institute of Technology (Indian School of Mines), Dhanbad, 826004, India

    B. Chowdhury

Authors
  1. S. E. Lyubimov
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  2. P. V. Cherkasova
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  3. B. Chowdhury
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Corresponding authors

Correspondence to S. E. Lyubimov or B. Chowdhury.

Additional information

Dedicated to the Corresponding Member of the Russian Academy of Sciences A. A. Trifonov on the occasion of his 60th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 404–407, February, 2022.

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Lyubimov, S.E., Cherkasova, P.V. & Chowdhury, B. The use of triethanolamine ammonium salts as catalysts for the addition of carbon dioxide to epoxides. Russ Chem Bull 71, 404–407 (2022). https://doi.org/10.1007/s11172-022-3426-1

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  • DOI: https://doi.org/10.1007/s11172-022-3426-1

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