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Complexing properties of N-[1,1-bis(hydroxymethyl)ethyl]-and N-[tris(hydroxymethyl)methyl]-β-alanine

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Abstract

Protolytic and complexing properties of N-[1,1-bis(hydroxymethyl)ethyl]- and N-[tris-(hydroxymethyl)methyl]-β-alanine were estimated using the potentiometry. Values of the dissociation constants of amino and carboxyl functional groups in molecules of these reagents, as well as the stability constants of their complexes of various compositions with copper(ii), cobalt(ii), nickel(ii), zinc(ii), cadmium(ii), silver(i), magnesium(ii), calcium(ii), strontium(ii), and barium(ii) ions, were calculated. The hydroxyalkylation of β-alanine tunes its properties towards the considered metal ions. Complexes of copper(ii) ions with these β-alanine derivatives are the most stable complex compounds among explored herein.

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Authors and Affiliations

  1. Ural Federal University named after the First President of Russia B. N. Yeltsin, 19 ul. Mira, 620002, Ekaterinburg, Russian Federation

    G. P. Zharkov, O. V. Filimonova, Yu. S. Petrova, A. V. Pestov & L. K. Neudachina

  2. I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 ul. S. Kovalevskoy, 620108, Ekaterinburg, Russian Federation

    A. V. Pestov

Authors
  1. G. P. Zharkov
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  2. O. V. Filimonova
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  3. Yu. S. Petrova
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  4. A. V. Pestov
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  5. L. K. Neudachina
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Corresponding author

Correspondence to G. P. Zharkov.

Additional information

Dedicated to Academician of the Russian Academy of Sciences O. M. Nefedov on the occasion of his 90th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 152–157, January, 2022.

This work was fi nancially supported by the Government of the Russian Federation (Decree No. 211, Contract No. 02.A03.21.0006) and carried out within the framework of the state assignment to the I. Ya. Postovsky Institute of Organic Synthesis of the Ural Branch of the Russian Academy of Sciences (Topic No. AAAA-A19-119012290117-6) using the equipment of the Center for Collective Use “Spectroscopy and Analysis of Organic Compounds”.

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Zharkov, G.P., Filimonova, O.V., Petrova, Y.S. et al. Complexing properties of N-[1,1-bis(hydroxymethyl)ethyl]-and N-[tris(hydroxymethyl)methyl]-β-alanine. Russ Chem Bull 71, 152–157 (2022). https://doi.org/10.1007/s11172-022-3389-2

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  • DOI: https://doi.org/10.1007/s11172-022-3389-2

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