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Solvent effect on the rate and direction of furfural transformations during hydrogenation over the Pd/C catalyst

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Abstract

The rate and directions of transformations during the liquid-phase hydrogenation of furfural with molecular hydrogen in the presence of the 5%Pd/C catalyst (at 423 K, 3 MPa) depend substantially on the chemical nature of the solvent. The main products of the catalytic transformations in alcohols are alkyl furyl ethers. Hydrogenation in solvent environment of aromatic hydrocarbons and 1,4-dioxane (nonpolar solvents), as well as in ethyl acetate and DMF (polar aprotic solvents) leads to the predominant formation of furfuryl alcohol, and its highest selectivity (up to 92%) is achieved with the use of DMF.

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Authors and Affiliations

  1. Center of New Chemical Technologies, Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 54 ul. Neftezavodskaya, 644040, Omsk, Russia

    R. M. Mironenko & O. B. Belskaya

  2. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrent’eva, 630090, Novosibirsk, Russia

    V. A. Likholobov

Authors
  1. R. M. Mironenko
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  2. O. B. Belskaya
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  3. V. A. Likholobov
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Corresponding authors

Correspondence to R. M. Mironenko or V. A. Likholobov.

Additional information

Dedicated to Academician of the Russian Academy of Sciences O. M. Nefedov on the occasion of his 90th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 64–69, January, 2022.

This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental order for the Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences (Project No. AAAA-A21-121011490008-3). Experiments (GC/MS, NMR) were carried out using the equipment of the shared research center “National Center of Investigation of Catalysts.”

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Mironenko, R.M., Belskaya, O.B. & Likholobov, V.A. Solvent effect on the rate and direction of furfural transformations during hydrogenation over the Pd/C catalyst. Russ Chem Bull 71, 64–69 (2022). https://doi.org/10.1007/s11172-022-3377-6

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  • DOI: https://doi.org/10.1007/s11172-022-3377-6

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