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Si3S-Bicyclo[1.1.0]butane vs. Si3S-cyclobutene: an isomeric interplay*

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Abstract

(Thiatrisila)bicyclo[1.1.0]butane 1 quantitatively transformed under either photochemical or thermal conditions into the isomeric (thiatrisila)cyclobutene 2, which was isolated and fully characterized.

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References

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Funding

This work was partially supported by the JSPS KAKENHI Grants program (No. JP21K05017) from the Ministry of Education, Science, Sports, and Culture of Japan, and by the Ministry of Science and Higher Education of the Russian Federation (State assignment in the fi eld of scientifi c activity, Southern Federal University, 2020, No. 0852-2020-0019).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, 305-8571, Tsukuba, Ibaraki, Japan

    V. Ya. Lee, S. Miyazaki & A. Sekiguchi

  2. Institute of Physical and Organic Chemistry, Southern Federal University, 194/2 prosp. Stachki, 344090, Rostov-on-Don, Russian Federation

    O. A. Gapurenko, R. M. Minyaev & V. I. Minkin

Authors
  1. V. Ya. Lee
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  2. S. Miyazaki
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  3. O. A. Gapurenko
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  4. R. M. Minyaev
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  5. V. I. Minkin
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  6. A. Sekiguchi
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Corresponding authors

Correspondence to V. Ya. Lee or A. Sekiguchi.

Additional information

Dedicated to Academician of the Russian Academy of Sciences O. M. Nefedov on the occasion of his 90th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2233–2235, November, 2021.

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Lee, V.Y., Miyazaki, S., Gapurenko, O.A. et al. Si3S-Bicyclo[1.1.0]butane vs. Si3S-cyclobutene: an isomeric interplay*. Russ Chem Bull 70, 2233–2235 (2021). https://doi.org/10.1007/s11172-021-3338-5

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  • DOI: https://doi.org/10.1007/s11172-021-3338-5

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