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Reaction of polyfluoroalkyl dichlorophosphites with propargyl alcohol: synthesis and isomerization of polyfluoroalkyl di(2-propynyl) phosphites

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Abstract

Polyfluoroalkyl dichlorophosphites reacted with propargyl alcohol in Et3N/hexane to give di(2-propynyl) polyfluoroalkyl phosphites, which are transformed into polyfluoroalkyl 2-propynyl allenylphosphonates and isomeric (1-propynyl)phosphonates upon storage.

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Authors and Affiliations

  1. A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation

    N. K. Gusarova, S. F. Malysheva, N. A. Belogorlova, S. I. Verkhoturova, S. N. Arbuzova, N. A. Chernysheva, P. A. Volkov & B. A. Trofimov

  2. D. V. Sokolskiy Institute of Fuel, Catalysis and Electrochemistry, 142 ul. Kunaeva, 050010, Almaty, Republic of Kazakhstan

    A. M. Nalibayeva & G. K. Bishimbayeva

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  1. N. K. Gusarova
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  2. S. F. Malysheva
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  3. N. A. Belogorlova
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Correspondence to B. A. Trofimov.

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Dedicated to Academician of the Russian Academy of Sciences O. M. Nefedov on the occasion of his 90th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2195–2199, November, 2021.

This work was performed using the equipment of the Baykal analytical center for collective use of the Siberian Branch of the Russian Academy of Science.

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Gusarova, N.K., Malysheva, S.F., Belogorlova, N.A. et al. Reaction of polyfluoroalkyl dichlorophosphites with propargyl alcohol: synthesis and isomerization of polyfluoroalkyl di(2-propynyl) phosphites. Russ Chem Bull 70, 2195–2199 (2021). https://doi.org/10.1007/s11172-021-3332-y

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