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Synthesis of energetic compounds bearing a (3,4-dinitro-1H-pyrazol-1-yl)-NNO-azoxy group

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Abstract

Energetic compounds containing a new explosophoric fragment, (3,4-dinitro-1H-pyrazol-1-yl)-NNO-azoxy group, and furazan rings linked by azo and azoxy bridges were synthesized. Furazans obtained combine a high calculated enthalpy of formation and acceptable thermal stability and are of interest as potential components of energy-rich materials.

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Funding

This work was financially supported by the Russian Science Foundation (Project No. 19-13-00276).

Author information

Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    A. A. Konnov, I. M. Dubrovin, M. S. Klenov, O. V. Anikin, A. M. Churakov, Yu. A. Strelenko & V. A. Tartakovsky

  2. N. N. Semenov Federal Research Center of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 119991, Moscow, Russian Federation

    A. N. Pivkina

Authors
  1. A. A. Konnov
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  2. I. M. Dubrovin
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  3. M. S. Klenov
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  4. O. V. Anikin
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  5. A. M. Churakov
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  6. Yu. A. Strelenko
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  7. A. N. Pivkina
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  8. V. A. Tartakovsky
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Corresponding author

Correspondence to M. S. Klenov.

Additional information

Dedicated to Academician of the Russian Academy of Sciences O. M. Nefedov on the occasion of his 90th birthday.

A. A. Konnov, M. S. Klenov, A. M. Churakov, I. M. Dubrovin, I. L. Dalinger, Yu. A. Strelenko, I. V. Fedyanin, D. B. Lempert, E. K. Kosareva, T. S. Kon’kova, Y. N. Matyushin, V. A. Tartakovsky, Novel energetic compounds containing(3,4-dinitro-1H-pyrazol-1-yl)-NNO-azoxy and (3,5-dinitro-1H-pyrazol-1-yl)-NNO-azoxy moieties: synthesis and characterization, Asian J. Org. Chem., 2021, in press.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2189–2194, November, 2021.

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Konnov, A.A., Dubrovin, I.M., Klenov, M.S. et al. Synthesis of energetic compounds bearing a (3,4-dinitro-1H-pyrazol-1-yl)-NNO-azoxy group. Russ Chem Bull 70, 2189–2194 (2021). https://doi.org/10.1007/s11172-021-3331-z

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