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Synthesis and copolymerization of new methacrylic monomers for the creation of nonlinear optical polymer materials

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Abstract

A new methacrylic monomer, 3,5-bis[2-(N-ethylanilino)ethoxy]benzyl methacrylate (MBA), has been synthesized. Methacrylic copolymers with different content of bi-chromophore fragments in the side chain were obtained by radical copolymerization of methyl methacrylate and MBA, followed by azo-functionalization reaction. The composition of the obtained copolymers was established, and their thermal properties were determined. Thin films of synthesized copolymers were prepared by spin-coating and the nonlinear optical characteristics of the obtained materials were investigated.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center Kazan Scientific Center, Russian Academy of Sciences, 8 ul. Acad. Arbuzov, 420088, Kazan, Russian Federation

    A. I. Gaisin, T. A. Vakhonina, A. Sh. Mukhtarov & M. Yu. Balakina

  2. Zavoisky Physical-Technical Institute, Federal Research Center Kazan Scientific Center, Russian Academy of Sciences, 10/7 Sibirsky tract, 420029, Kazan, Russian Federation

    A. G. Shmelev

Authors
  1. A. I. Gaisin
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  2. T. A. Vakhonina
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  3. A. Sh. Mukhtarov
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  4. A. G. Shmelev
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  5. M. Yu. Balakina
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Corresponding author

Correspondence to T. A. Vakhonina.

Additional information

Based on the materials of the VIII All-Russian Kargin Conference “Polymer-2020” (November 9–13, 2020, Moscow, Russia).

Published in Russian in Izyestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1757–1764, September, 2021.

The authors are grateful to the Collective Spectro-Analytical Center for Physicochemical Research of the Structure, Properties and Composition of Substances and Materials of the Federal Research Center Kazan Scientific Center of the Russian Academy of Sciences for technical support of the studies.

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Gaisin, A.I., Vakhonina, T.A., Mukhtarov, A.S. et al. Synthesis and copolymerization of new methacrylic monomers for the creation of nonlinear optical polymer materials. Russ Chem Bull 70, 1757–1764 (2021). https://doi.org/10.1007/s11172-021-3280-6

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  • DOI: https://doi.org/10.1007/s11172-021-3280-6

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