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Synthesis and dynamic mechanical properties of cross-linked multiblock poly(urethane-imide) copolymers

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Abstract

Poly(urethane-imide) copolymers (PUICs) containing reactive carboxyl groups in hard imide segment were synthesized from poly(propylene glycol) with isocyanate end groups, 1,3-bis(3′,4′-dicarboxyphenoxy)benzene dianhydride, aromatic diamines 4,4′-bis(4″-aminophenoxy)diphenyl sulfone or 4,4′-bis-(4″-aminophenoxy)biphenyl, and 3,5-diaminobenzoic acid. The PUICs were covalently cross-linked using reactions of carboxyl groups with aromatic diisocyanates and 1,2,5,6-diepoxycyclooctane. The polymers obtained were studied by thermogravimetric analysis, differential scanning calorimetry, and dynamic mechanical analysis. It was shown that the structure of the cross-linking agents influences the properties of cross-linked PUICs. Changes in the mechanical loss factor (tg δ) were analyzed vs. chemical structure of the PUICs. The maximum tg δ values of the copolymers studied are in the range of 0.3–0.4, which suggests good damping capacity of these systems.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, 31 Bolshoy prosp., 199004, St. Petersburg, Russian Federation

    A. L. Didenko, A. G. Ivanov, V. E. Smirnova, G. V. Vaganov, E. N. Popova, D. A. Kuznetsov, V. M. Svetlichniy, V. E. Yudin & V. V. Kudryavtsev

  2. Peter The Great St. Petersburg Polytechnic University, 29 Politekhnicheskaya ul., 195251, St. Petersburg, Russian Federation

    E. A. Bogdanova, I. A. Kobykhno, E. S. Vasiliyeva & O. V. Tolochko

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  1. A. L. Didenko
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  2. A. G. Ivanov
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  3. E. A. Bogdanova
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  4. V. E. Smirnova
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  5. G. V. Vaganov
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  6. E. N. Popova
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  7. D. A. Kuznetsov
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  8. I. A. Kobykhno
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  9. E. S. Vasiliyeva
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  10. O. V. Tolochko
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  11. V. M. Svetlichniy
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  12. V. E. Yudin
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  13. V. V. Kudryavtsev
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Corresponding author

Correspondence to A. L. Didenko.

Additional information

Based on the materials of the VIII All-Russia Kargin Conference “Polymers-2020” (November 9–13, 2020, Moscow, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1746–1756, September, 2021.

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Didenko, A.L., Ivanov, A.G., Bogdanova, E.A. et al. Synthesis and dynamic mechanical properties of cross-linked multiblock poly(urethane-imide) copolymers. Russ Chem Bull 70, 1746–1756 (2021). https://doi.org/10.1007/s11172-021-3279-z

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  • DOI: https://doi.org/10.1007/s11172-021-3279-z

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