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Synthesis of polylactic acid by the solid-state polycondensation of oligomers. Effect of the nanosized boron filler on the final properties of the polymer

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Abstract

A method developed for producing composites based on polylactic acid (PLA) and elemental boron nanoparticles by the method of solid-state polycondensation is presented. The synthesis parameters (time, temperature, and residual pressure) were optimized to obtain PLA with desired properties. The influence of the nanosized boron filler was evaluated. When boron nanoparticles are added in an amount of 0.03 wt.%, the properties of PLA change: the degree of crystallinity increases by 20% compared to the polymer without additives and an increase in the molecular weight of the polymer up to 60 kDa is observed. The properties of the solid-state polycondensation products were studied by NMR spectroscopy, X-ray phase analysis, gel-permeation chromatography, and differential scanning calorimetry.

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Authors and Affiliations

  1. N. S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 70 ul. Profsoyuznaya, 117393, Moscow, Russian Federation

    P. A. Khaptakhanova, N. B. Svishcheva, T. S. Kurkin & S. A. Uspenskii

  2. Autonomous Non-profit Organization “International Research Center for Innovative Technologies MARTINEX,”, Build. 3, 12 yl. 2-ya Vladimirskaya, 111123, Moscow, Russian Federation

    P. A. Khaptakhanova & S. A. Uspenskii

Authors
  1. P. A. Khaptakhanova
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  2. N. B. Svishcheva
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  3. T. S. Kurkin
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  4. S. A. Uspenskii
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Corresponding authors

Correspondence to P. A. Khaptakhanova or S. A. Uspenskii.

Additional information

Based on the materials of the VIII All-Russian Kargin Conference “Polymers-2020” (November 9–13, 2020, Moscow, Russia).

Published in Russian in Izvestiya AkademiiNauk. Seriya Khimicheskaya, No. 9, pp. 1729–1735, September, 2021.

This work was financially supported by the Russian Foundation for Basic Research (Project No. 20-33-90283).

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Khaptakhanova, P.A., Svishcheva, N.B., Kurkin, T.S. et al. Synthesis of polylactic acid by the solid-state polycondensation of oligomers. Effect of the nanosized boron filler on the final properties of the polymer. Russ Chem Bull 70, 1729–1735 (2021). https://doi.org/10.1007/s11172-021-3277-1

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  • DOI: https://doi.org/10.1007/s11172-021-3277-1

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