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Modification of the mechanism of proton conductivity of the perfluorinated membrane copolymer by nanodiamonds

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Abstract

Proton conducting membranes based on a perfluorinated copolymer with short side chains (of the Aquivion® type) are promising for the use in hydrogen fuel cells and overcome in characteristics traditionally used long-chain membranes of the Nation® type. To improve the characteristics of Aquivion® membranes, we used modifying additives in the form of functionalized nanodiamonds. The mechanism of proton conductivity of composite membranes with nanodiamonds is modified by introducing additional ionogenic groups into the structure on the surface of nanodiamonds. The dependences of the conductivity and mechanical properties of the prepared composite membranes on the sign of the surface charge of the introduced nanodiamonds are examined.

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Authors and Affiliations

  1. Petersburg Nuclear Physics Institute named by B. P. Konstantinov of National Research Center “Kurchatov Institute,”, 1 Orlova Roshcha, 188300, Gatchina, Leningrad Region, Russian Federation

    Yu. V. Kulvelis & V. T. Lebedev

  2. Institute of Macromolecular Compounds, Russian Academy of Sciences, 31 Bol’shoi prosp. V. O., 199004, St. Petersburg, Russian Federation

    O. N. Primachenko, I. V. Gofman, A. S. Odinokov & E. A. Marinenko

  3. Russian Research Center of Applied Chemistry, 26A ul. Krylenko, 193232, St. Petersburg, Russian Federation

    A. S. Odinokov

  4. Ioffe Institute, 26 Polytekhnicheskaya ul., 194021, St. Petersburg, Russian Federation

    A. V. Shvidchenko, E. B. Yudina & A. Ya. Vul

Authors
  1. Yu. V. Kulvelis
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  2. O. N. Primachenko
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  3. I. V. Gofman
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  4. A. S. Odinokov
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  5. A. V. Shvidchenko
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  6. E. B. Yudina
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  7. E. A. Marinenko
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  8. V. T. Lebedev
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  9. A. Ya. Vul
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Corresponding author

Correspondence to Yu. V. Kulvelis.

Additional information

Based on the materials of the VIII All-Russian Kargin Conference “Polymers-2020” (November 9–13, 2020, Moscow, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1713–1717, September, 2021.

This work was financially supported by the Ministry of Education and Science of the Russian Federation (Project No. 121040200129-2). The authors (Yu. V. Kulvelis, A. V. Shvidchenko, E. B. Yudina, V. T. Lebedev, and A. Ya. Vul) are grateful to the Russian Foundation for Basic Research for partial support of the present studies (Project No. 19-03-00249 A).

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Kulvelis, Y.V., Primachenko, O.N., Gofman, I.V. et al. Modification of the mechanism of proton conductivity of the perfluorinated membrane copolymer by nanodiamonds. Russ Chem Bull 70, 1713–1717 (2021). https://doi.org/10.1007/s11172-021-3274-4

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  • DOI: https://doi.org/10.1007/s11172-021-3274-4

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