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Structural variety of CdS in films synthesized by vapor deposition polymerization

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Abstract

Poly(p-xylylene)—CdS (PPX—CdS) nanocomposite films with different thicknesses (∼0.2, ∼0.5, ∼1, and ∼1.5 μm) and concentrations of CdS from 5 to 90 vol.%, as well as single-component CdS and PPX films with various thicknesses were studied by X-ray diffraction. The films were synthesized on polished silicon or quartz substrates by low-temperature vapor deposition method. It was shown that CdS nanoparticles in PPX—CdS films, depending on their thickness and CdS content, can have an X-ray amorphous structure, a defect crystal structure (RCP structure), or a wurtzite-type crystal structure. Similar structures were observed for single-component CdS films of the corresponding thickness. The sizes of the coherent scattering regions of CdS were determined for some nanocomposite and single-component films. Poly(p-xylylene) in the studied nanocomposite films was characterized by an X-ray amorphous structure.

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References

  1. E. I. Grigor’ev, S. A. Zav’yalov, S. N. Chvalun, Rossiyskie Nanotekhnologii [RussianNanotechnologies], 2006, 1, No. 1–2, 58 (in Russian).

    Google Scholar 

  2. A. V. Gusev, K. A. Mailyan, A. V. Pebalk, I. A. Ryzhikov, S. N. Chvalun, Radiotekhnika and Elektronika [Radio Engineering and Electronics], 2009, 54, No. 7, 875 (in Russian).

    CAS  Google Scholar 

  3. A. A. Nesmelov, L. N. Oveshnikov, S. A. Ozerin, S. A. Zav’yalov, Ya. V. Zubavichus, A. S. Orekhov, D. R. Streltsov, Yu. I. Kiryukhin, S. N. Chvalun, J. Phys. Chem. C, 2019, 123, 10517.

    Article  CAS  Google Scholar 

  4. P. V. Morozov, E. I. Grigoriev, S. A. Zavyalov, S. N. Chvalun, Sov. Phys. Sol. State (Engl. Transl.), 2012, 54, 2291.

    Article  CAS  Google Scholar 

  5. A. A. Rempel, A. A. Valeeva, Russ. Chem. Bull., 2019, 68, 2163.

    Article  CAS  Google Scholar 

  6. T. V. Samofalova, V. N. Semenov, Russ. Chem. Bull., 2020, 69, 1755.

    Article  CAS  Google Scholar 

  7. I. A. Misurkin, S. V. Titov, T. S. Zhuravleva, I. V. Klimeyko, S. A. Zavyalov, E. I. Grigoryev, S. N. Chvalun, Russ. J. Phys. Chem. A, 2009, 83, 450.

    Article  CAS  Google Scholar 

  8. T. S. Zhuravleva, O. P. Ivanova, E. P. Krinichnaya, I. A. Misurkin, S. V. Titov, S. A. Zav’yalov, E. I. Grigor’ev, Russ. J. Phys. Chem. B, 2011, 5, 681.

    Article  CAS  Google Scholar 

  9. O. P. Ivanova, E. P. Krinichnaya, S. A. Zavyalov, T. S. Zhuravleva, Nanotechnologies in Russia, 2017, 12, 627.

    Article  CAS  Google Scholar 

  10. O. P. Ivanova, E. P. Krinichnaya, P. V. Morozov, S. A. Zavyalov, T. S. Zhuravleva, Nanotechnologies in Russia, 2019, 14, 7.

    Article  CAS  Google Scholar 

  11. M. P. Slavinskii, Fiziko-khimicheskie svoystva elementov [Physicochemical Properties of Elements], Moscow, Metallurgizdat, 1952, 188 pp. (in Russian).

    Google Scholar 

  12. S. A. Zavyalov, A. N. Pivkina, J. Schoonman, Solid State Ionics, 2002, 147, 415.

    Article  CAS  Google Scholar 

  13. A. V. Krivandin, A. B. Solov’eva, N. N. Glagolev, O. V. Shatalova, S. L. Kotova, Polymer, 2003, 44, 5789.

    Article  CAS  Google Scholar 

  14. R. Benerjee, R. Jayakrishnan, P. Ayyub, J. Phys. Condens. Matter., 2000, 12, 10647.

    Article  Google Scholar 

  15. N. S. Kozhevnikova, A. S. Vorokh, A. A. Uritskaya, Russ. Chem. Rev., 2015, 84, 225.

    Article  Google Scholar 

  16. A. S. Vorokh, A. A. Rempel, Dokl. Phys. (Engl. Transl.), 2007, 52, 200.

    Article  CAS  Google Scholar 

  17. A. S. Vorokh, N. S. Kozhevnikova, A. A. Rempel, Bull. Russ. Acad. Sci., Physics, 2008, 72, 1395.

    Article  Google Scholar 

  18. B. K. Vainshtein, Difraktsiya rentgenovskikh luchei na tsepnykh molekulakh [X-ray Diffraction on Chain Molecules], Moscow, Izd-vo AN SSSR, 1963 (in Russian).

    Google Scholar 

  19. C. F. Holder, R. E. Schaak, ACS Nano, 2019, 13, 7359.

    Article  CAS  Google Scholar 

  20. N. Herron, Y. Wang, H. Eckert, J. Am. Chem. Soc., 1990, 112, 1322.

    Article  CAS  Google Scholar 

  21. S. Kubo, B. Wunderlich, J. Polym. Sci. Polym. Phys. Ed., 1972, 10, 1949.

    CAS  Google Scholar 

  22. G. Treiber, K. Boehlke, A. Weitz, B. Wunderlich, J. Polym. Sci. Polym. Phys. Ed., 1973, 11, 1111.

    Article  CAS  Google Scholar 

  23. M. Gazicki, G. Surendran, W. James, H. Yasuda, J. Polym. Sci., Part A. Polym. Chem. Phys., 1986, 24, 215.

    Article  CAS  Google Scholar 

  24. D. R. Streltsov, K. A. Mailyan, A. V. Gusev, Polymer, 2015, 71, 60.

    Article  CAS  Google Scholar 

  25. K. A. Mailyan, S. N. Chvalun, A. V. Pebalk, I. E. Kardash, Polym. Sci., Ser. A (Engl. Transl.), 1992, 34, 761.

    Google Scholar 

  26. A. A. Knyazeva, S. A. Ozerin, E. I. Grigoriev, S. N. Chvalun, S. A. Zavyalov, I. E. Kardash, J. Polym. Sci., Ser. B (Engl. Transl.), 2005, 47, 206.

    Google Scholar 

  27. D. R. Streltsov, K. A. Mailyan, A. V. Gusev, Appl. Phys. A, 2013, 110, 413.

    Article  CAS  Google Scholar 

  28. Y. Wang, N. Herron, Phys. Rev. B, 1990, 42, 7253.

    Article  CAS  Google Scholar 

  29. T. Vossmeyer, L. Katsikas, M. Giersig, I. G. Popovic, J. Phys. Chem., 1994, 98, 7665.

    Article  CAS  Google Scholar 

  30. M. Gazicki, G. Surendran, W. James, H. Yasuda, J. Polym. Sci., Polym. Chem. Ed., 1985, 23, 2255.

    Article  CAS  Google Scholar 

  31. D. R. Streltsov, A. I. Buzin, P. V. Dmitryakov, N. P. Bessonova, P. Kamasa, D. A. Ivanov, S. N. Chvalun, Thermochimica Acta, 2013, 573, 175.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 119334, Moscow, Russian Federation

    O. P. Ivanova, A. V. Krivandin & T. S. Zhuravleva

  2. National Research Center Kurchatov Institute, 1 pl. Akad. Kurchatova, 123182, Moscow, Russian Federation

    S. A. Zav’yalov

Authors
  1. O. P. Ivanova
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  2. A. V. Krivandin
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  3. S. A. Zav’yalov
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  4. T. S. Zhuravleva
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Corresponding author

Correspondence to O. P. Ivanova.

Additional information

Published in Russian in Izvestiya AkademiiNauk. Seriya Khimicheskaya, No. 9, pp. 1699–1705, September, 2021.

This work was financially supported within the framework of the state assignment of the Institute of Biochemical Physics of the Russian Academy of Sciences (Project No. 01201253304) and by the Russian Foundation for Basic Research (Project No. 18-03-00582).

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Ivanova, O.P., Krivandin, A.V., Zav’yalov, S.A. et al. Structural variety of CdS in films synthesized by vapor deposition polymerization. Russ Chem Bull 70, 1699–1705 (2021). https://doi.org/10.1007/s11172-021-3272-6

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  • DOI: https://doi.org/10.1007/s11172-021-3272-6

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