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Chiral recognition of N-thiophosphorylated thioureas via nickel(ii) coordination assisted by 4-dimethylaminopyridine

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Abstract

Nickel(ii) complexes were synthesized using chiral N-thiophosphorylated thioureas as the starting compounds and 4-dimethylaminopyridine as a co-ligand. The reaction with racemic thiourea afforded homochiral complexes due to the distortion of the nickel coordination. The unsaturated coordination sphere of nickel ions results in the formation of supramolecular homochiral 1D chains in the crystal through steric key—lock interactions between adjacent molecules. Conformational flexibility of the ligands is responsible for disorder of molecules in the crystals and the occurrence of polymorphs.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of Russian Academy of Sciences”, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    K. E. Metlushka, D. N. Sadkova, K. A. Nikitina, R. G. Zinnatullin, Z. R. Yamaleeva, K. A. Ivshin & O. N. Kataeva

  2. A. M. Butlerov Chemical Institute, Kazan Federal University, 18 ul. Kremlevskaya, 420008, Kazan, Russian Federation

    K. A. Ivshin & O. N. Kataeva

  3. Institute of Physics, Kazan Federal University, 18 ul. Kremlevskaya, 420008, Kazan, Russian Federation

    A. G. Kiiamov

Authors
  1. K. E. Metlushka
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  2. D. N. Sadkova
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  3. K. A. Nikitina
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  4. R. G. Zinnatullin
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  5. Z. R. Yamaleeva
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  6. K. A. Ivshin
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  7. A. G. Kiiamov
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  8. O. N. Kataeva
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Corresponding author

Correspondence to O. N. Kataeva.

Additional information

Based on the materials of the II Scientific Conference “Dynamic Processes in the Chemistry of Organoelement Compounds” (November 11–13, 2020, Kazan, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1304–1310, July, 2021.

This study was financially supported by the Russian Foundation for Basic Research (Project No. 20-03-00572) and a subsidy allocated to the Kazan Federal University for the implementation of the state assignment in the field of scientific activity (Project No. 0671-2020-0063).

We gratefully acknowledge the Spectral-Analytical Center of the Federal Research Center of Kazan Scientific Center of Russian Academy of Sciences (CSF-SAC FRC KSC RAS) for providing necessary facilities to carry out this work.

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Metlushka, K.E., Sadkova, D.N., Nikitina, K.A. et al. Chiral recognition of N-thiophosphorylated thioureas via nickel(ii) coordination assisted by 4-dimethylaminopyridine. Russ Chem Bull 70, 1304–1310 (2021). https://doi.org/10.1007/s11172-021-3215-2

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  • DOI: https://doi.org/10.1007/s11172-021-3215-2

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