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Metal complexes of tetrakis(2-carboxyphenylsulfanyl)phthalocyanine. Synthesis, spectral and catalytic properties

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Abstract

Carboxylic acid sodium salts of the phthalocyanine derivatives with phenylsulfanyl fragments at the periphery containing MgII, CoII, CuII, and ZnII ions as central metal atoms were synthesized. The aggregation behavior of all metal complexes in a water-alkaline solution was considered. The luminescence properties of the phthalocyanine derivatives with MgII and ZnII were studied. The catalytic properties were studied for the macrocycles with CoII, CuII, and ZnII.

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Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, 7 Sheremetevskii prosp., 153000, Ivanovo, Russian Federation

    A. A. Botnar’, N. P. Domareva, D. A. Erzunov, N. A. Futerman, T. V. Tikhomirova, V. E. Maizlish & A. S. Vashurin

Authors
  1. A. A. Botnar’
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  2. N. P. Domareva
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  3. D. A. Erzunov
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  4. N. A. Futerman
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  5. T. V. Tikhomirova
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  6. V. E. Maizlish
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  7. A. S. Vashurin
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Corresponding author

Correspondence to A. A. Botnar’.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1297–1303, July, 2021.

This work was financially supported by the Russian Science Foundation (Project No. 17-73-20017) using the equipment of the Center for Collective Use of the Ivanovo State University of Chemistry and Technology.

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Botnar’, A.A., Domareva, N.P., Erzunov, D.A. et al. Metal complexes of tetrakis(2-carboxyphenylsulfanyl)phthalocyanine. Synthesis, spectral and catalytic properties. Russ Chem Bull 70, 1297–1303 (2021). https://doi.org/10.1007/s11172-021-3214-3

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  • DOI: https://doi.org/10.1007/s11172-021-3214-3

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