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Rotational conformation of 8,8′-dihalogenated derivatives of cobalt bis(dicarbollide) in solution

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Abstract

The 1H NMR study demonstrated that the transoid conformation of dihalogenated derivatives of cobalt bis(dicarbollide) [8,8′-X2-3,3′-Co(1,2-C2B9H10)2]− (X = Cl, Br, I), stabilized by intramolecular \(\text{C} - \text{H} \cdots \text{X}\) hydrogen bonds between ligands, is retained in solution.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    I. B. Sivaev & I. D. Kosenko

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  1. I. B. Sivaev
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  2. I. D. Kosenko
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Correspondence to I. B. Sivaev.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 753–756, April, 2021.

The work was financially supported by the Russian Science Foundation (Project No. 16-13-10331). The NMR spectra were recorded using equipment of the Center for Molecular Composition Studies at the A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences operating with the financial support from the Ministry of Science and Higher Education of the Russian Federation.

No human or animal subjects were involved in this research.

The authors declare no conflict of interest, financial or otherwise.

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Sivaev, I.B., Kosenko, I.D. Rotational conformation of 8,8′-dihalogenated derivatives of cobalt bis(dicarbollide) in solution. Russ Chem Bull 70, 753–756 (2021). https://doi.org/10.1007/s11172-021-3146-y

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  • DOI: https://doi.org/10.1007/s11172-021-3146-y

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