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Poly(methoxy-NNO-azoxyethene), a new polymer for active binders in solid composite propellants

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Abstract

Radical polymerization of unsaturated alkoxy-NNO-azoxy compounds was explored. Polymethoxy-NNO-azoxyethene, the first energetic polymer based on alkoxy-NNO-azoxy compounds, was obtained, and its major characteristics were studied. Thermodynamic calculations show that poly(methoxy-NNO-azoxyethene) may be of interest as a polymer component of active binders for solid composite rocket propellants.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russin Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    V. P. Grachev, I. N. Zyuzin, S. V. Kurmaz, E. V. Vaganov, R. I. Komendant & D. B. Lempert

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  1. V. P. Grachev
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  2. I. N. Zyuzin
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  3. S. V. Kurmaz
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  4. E. V. Vaganov
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  5. R. I. Komendant
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  6. D. B. Lempert
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Correspondence to V. P. Grachev.

Additional information

This work was performed within the framework of the state tasks (Project Nos. AAAA-A19-119101690058-9 and AAAA-A19-119041090087-4).

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Grachev, V.P., Zyuzin, I.N., Kurmaz, S.V. et al. Poly(methoxy-NNO-azoxyethene), a new polymer for active binders in solid composite propellants. Russ Chem Bull 69, 2312–2319 (2020). https://doi.org/10.1007/s11172-020-3037-7

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  • DOI: https://doi.org/10.1007/s11172-020-3037-7

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