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Synthesis and crystal structure of new coordination polymers based on sodium aqua complexes and macrocyclic cavitand cucurbit[6]uril

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Abstract

The crystals of the compounds [Na4(H2O)14CB[6]](bdc)2 · 13H2O (1) and [Na6(H2O)19CB[6]]-(bdc)3 ·15H2O (2) were obtained by heating an aqueous solution of sodium terephthalate (Na2bdc) and cucurbit[6]uril (CB[6]). According to the single-crystal X-ray diffraction data, the sodium aqua complexes and cucurbit[6]uril molecules form chains (in structure 1) and layered metal-organic frameworks (in structure 2). The structures of the sodium aqua complexes [Na3(H2O)10]3+ in 1 and [Na6(H2O)19]3+ in 2 have been previously unknown. When submitted to ultraviolet radiation, crystals of 1 and 2 exhibit luminescence with an emission maximum at 428 and 434 nm, respectively.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    I. V. Andrienko, E. A. Kovalenko, D. G. Samsonenko & V. P. Fedin

Authors
  1. I. V. Andrienko
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  2. E. A. Kovalenko
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  3. D. G. Samsonenko
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  4. V. P. Fedin
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Corresponding author

Correspondence to V. P. Fedin.

Additional information

We thank M. I. Rakhmanova for recording photoluminescence spectra.

This study was performed within the framework of the basic budget financing.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2113—2120, November, 2020.

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Andrienko, I.V., Kovalenko, E.A., Samsonenko, D.G. et al. Synthesis and crystal structure of new coordination polymers based on sodium aqua complexes and macrocyclic cavitand cucurbit[6]uril. Russ Chem Bull 69, 2113–2120 (2020). https://doi.org/10.1007/s11172-020-3008-z

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  • DOI: https://doi.org/10.1007/s11172-020-3008-z

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